HIGH-POWER DENSITY PROTON-EXCHANGE MEMBRANE FUEL-CELLS

Proton-exchange membrane (PEM) fuel cells use a perfluorosulfonic acid solid polymer film as an electrolyte which simplifies water and electrolyte management. Their thin electrolyte layers give efficient systems of low weight, and their materials of construction show extremely long laboratory lifetimes. Their high reliability and their suitability for use in a microgravity environment makes them particularly attractive as a substitute for batteries in satellites utilizing high power, high energy-density electrochemical energy storage systems. In this investigation, the Dow experimental PEM (XUS-13204.10) and unsupported high platinum loading electrodes yielded very high power densities, of the order of 2.5 W cm(-2). A platinum black loading of 5 mg cm(-2) was found to be optimum. On extending the three-dimensional reaction zone of fuel cell electrodes by impregnating solid-polymer electrolyte into the electrode structures, Nafion(R) was found to give better performance than the Dow experimental PEM. The depth of penetration of the solid polymer electrolyte into electrode structures was 50-70% of the thickness of the platinum-catalyzed active layer. However, the degree of platinum utilization was only 16.6% and the roughness factor of a typical electrode was 274.