Crystal structure of 4-bromo-N-(2-hydroxyphenyl)benzamide

被引:1
|
作者
Moreno-Fuquen, Rodolfo [1 ]
Melo, Vanessa [1 ]
Ellena, Javier [2 ]
机构
[1] Univ Valle, Fac Ciencias Nat & Exactas, Dept Quim, Santiago Cali, Colombia
[2] Univ Sao Paulo, Inst Fis Sao Carlos, Sao Carlos, SP, Brazil
关键词
crystal structure; benzamide; hydroxyaniline; hydrogen bonding;
D O I
10.1107/S1600536814024696
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C13H10BrNO2, the mean plane of the non-H atoms of the central amide C-N-C(O)-C fragment (r.m.s. deviation = 0.004 angstrom) forms a dihedral angle of 73.97 (12)degrees with the hydroxy-substituted benzene ring and 25.42 (19)degrees with the bromo-substituted benzene ring. The two aromatic rings are inclined to one another by 80.7 (2)degrees. In the crystal, molecules are linked by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, forming chains along [ 010]. The chains are linked by weak C-H center dot center dot center dot O hydrogen bonds, forming sheets parallel to (100), and enclosing R-3(3)(17) and R-2(3)(9) ring motifs.
引用
收藏
页码:O1261 / +
页数:8
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