1,2,3-TRIAMINOGUANIDINIUM AZIDE (TAZ) STRUCTURE

被引：2
|
作者：
BRACUTI, AJ [1 ]
EXTINE, MW [1 ]
机构：
[1] MOLEC STRUCT CORP,COLLEGE STN,TX 77840
来源：
JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1990年 / 20卷 / 01期
关键词：
D O I：
10.1007/BF01181672
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Triaminoguanidinium azide (TAZ) crystallizes in the monoclinic space group P21/c with a=6.679(2), b=7.722(2), c=13.143(4) Å, β=95.44(2)°, Z=4, with one anion/cation pair in the asymmetric unit. The structure was solved by direct methods and refined to a final R value of 0.037. The non-hydrogen atoms of the triaminoguanidinium cation are planar and the azide anion is linear. This puckered layer structure consists of an infinite three-dimensional network of N-H⋯N hydrogen bonds which link the cations to the anions. © 1990 Plenum Publishing Corporation.
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页码：31 / 35
页数：5
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