1,2,3-TRIAMINOGUANIDINIUM AZIDE (TAZ) STRUCTURE

被引：2

作者：

BRACUTI, AJ ^{[1
]}

EXTINE, MW ^{[1
]}

机构：

[1] MOLEC STRUCT CORP,COLLEGE STN,TX 77840

来源：

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1990年 / 20卷 / 01期

关键词：

D O I：

10.1007/BF01181672

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Triaminoguanidinium azide (TAZ) crystallizes in the monoclinic space group P21/c with a=6.679(2), b=7.722(2), c=13.143(4) Å, β=95.44(2)°, Z=4, with one anion/cation pair in the asymmetric unit. The structure was solved by direct methods and refined to a final R value of 0.037. The non-hydrogen atoms of the triaminoguanidinium cation are planar and the azide anion is linear. This puckered layer structure consists of an infinite three-dimensional network of N-H⋯N hydrogen bonds which link the cations to the anions. © 1990 Plenum Publishing Corporation.

引用

页码：31 / 35

页数：5

共 50 条

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