KINETICS AND MECHANISM OF FORMATION OF DICHLOROMONO-(AMIDINOTHIOUREA)PLATINUM(II) FROM PTCL42- AND AMIDINOTHIOUREA IN AQUEOUS ACID CHLORIDE MEDIUM

被引：0

作者：

MALLICK, M ^{[1
]}

BANERJEA, D ^{[1
]}

机构：

[1] UNIV CALCUTTA,UNIV COLL SCI,DEPT CHEM,LAB SIR RASHBEHARY GHOSE PROF CHEM,CALCUTTA 700009,W BENGAL,INDIA

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 1993年 / 70卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetics of formation of dichloromono(amidinothiourea)platinum(II) from PtCl4(2)- and amidinothiourea in acidic aqueous solution have been studied. The protonation constant of the ligand, amidinothiourea (L), and the equilibrium constants for the following reactions have been evaluated: [GRAPHICS] From the observed dependence of the rate of the reaction on concentrations of the ligand, H+ and Cl- ions, a plausible mechanism has been proposed. Activation parameters corresponding to the resolved rate constants have also been evaluated.

引用

页码：741 / 748

页数：8

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