Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution

被引:14
|
作者
Wang, Ruiping [1 ]
Itoh, Mitsuru [2 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, 1-1-1 Umezono, Tsukuba, Ibaraki 3058568, Japan
[2] Tokyo Inst Technol, Mat & Struct Lab, 4259 Nagatsuta, Yokohama, Kanagawa 2268503, Japan
关键词
Lead-free; piezoelectric; niobate; phase transition;
D O I
10.1142/S2010135X16500144
中图分类号
O59 [应用物理学];
学科分类号
摘要
Phase diagram of (1 - x)Na0.5K0.5NbO3-x(Bi0.5Na0.5)ZrO3 solid solution has been established from dielectric constant measurements and structure analyses. It is found that with increasing x, the C-T phase transition temperature TC-T and the T-O phase transition temperature TT-O decrease, while the O - R phase transition temperature TO-R increases. TT-O of NKN-xBNZ is much different from that of NKN-xBZ solid solution. The result could be mainly elucidated by the hybridization between the A-site ion and oxygen.
引用
收藏
页数:5
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