ENANTIODIFFERENTIATING TRANSFORMATION OF PROCHIRAL 1,3,5-PENTANETRIOLS CONTROLLED BY INTRAMOLECULAR VANDERWAALS ATTRACTIONS

被引：21
|
作者：
HARADA, T
WADA, I
UCHIMURA, JJ
INOUE, A
TANAKA, S
OKU, A
机构：
[1] Department of Chemistry, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期
关键词：
D O I：
10.1016/S0040-4039(00)92049-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acetalization of prochiral 1,3,5-pentanetriol derivatives (5) with l-menthone proceeded enantioselectively (3.0-4.6:1) to give chiral spiroacetals (6) which can be utilized as versatile chiral building blocks.
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页码：1219 / 1222
页数：4
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