trans-Bis[4-amino-N-(pyrimidin-2-yl-kappa N) benzenesulfonamidato-kappa N] bis(N, N-dimethylformamide-kappa O) cobalt(II)

被引：3
|
作者：
Guo, Jing Jing [1 ]
Wang, Wei [1 ]
Zhang, Yi Dong [1 ]
Yang, Li [1 ]
Zhang, Shu Hua [1 ]
机构：
[1] Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1107/S160053681204336X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Co(C10H9N4O2S)(2)(C3H7NO)(2)], lies across an inversion center. The Co-II atom is coordinated in a slightly distorted octahedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl) benzenesulfonamidate (sulfadiazine) anions and two O atoms from two dimethylformamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings is 82.37 (13)degrees. A three-dimensional network is generated by N-H center dot center dot center dot O hydrogen bonds between the amino groups and of the sulfonamidate O atoms of neighbouring molecules. The DMF ligand is disordered over two sets of sites in a 0.559 (4):0.441 (4) ratio.
引用
收藏
页码：M1398 / +
页数：10
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