MATHEMATICAL SIMULATION OF THE RADIATION-CHEMICAL PROCESSES IN HCLO4 SOLUTIONS

被引：0

作者：

VLADIMIROVA, MV

机构：

来源：

HIGH ENERGY CHEMISTRY | 1995年 / 29卷 / 05期

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D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mathematical simulation of the radiolysis of aqueous solutions of HClO4 (0.5 - 12 mol/l) under X-ray irradiation was performed. An optimal scheme of radiation-chemical reactions was adopted. It was demonstrated that the calculated and experimental yields of ClO3- ions are in good agreement if the yield of ClO3- formation by a direct-action mechanism is taken equal to 3.2 ion/100 eV. By comparing the calculated and experimental yields and the rate curves of ClO2 and Cl- formation, the reaction rate constants of HO2 radicals with ClO2- and ClO2 and of ClO radicals with H2O2 were found.

引用

页码：304 / 309

页数：6

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