KINETICS OF THE FREE-RADICAL POLYMERIZATION OF DIMETHYL DIALLYL AMMONIUM-CHLORIDE, .5. KINETIC-MODEL WITH PERSULFATE AS INITIATOR

被引：41
|
作者：
HAHN, M
JAEGER, W
机构：
[1] Institut Für Polymerenchemie, Teltow, D-1530
[2] Fraunhofer‐Einrichtung für Angewandte Polymerforschung, Teltow, D-O-1530
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1992年 / 198卷
关键词：
D O I：
10.1002/apmc.1992.051980114
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polymerization of dimethyl diallyl ammonium chloride in concentrated aqueous solution with persulfate as an initiator can be described up to high conversion by a kinetic model including a) formation of primary radicals by activated initiator decomposition as well as by redox reaction of S2O82- and Cl-, b) chain propagation via monomer cation associates and c) termination by combination of cyclized polymer radicals between each other or with chlorine atoms. A kinetic expression for the rate of polymerization is presented; rate constants and model parameters have been determined.
引用
收藏
页码：165 / 178
页数：14
相关论文
共 50 条
  • [21] INVESTIGATION OF THE RADICAL COPOLYMERIZATION OF DIMETHYL DIALLYL AMMONIUM-CHLORIDE AND VINYL-ACETATE AND FUNCTIONALIZATION REACTIONS OF THE RESPECTIVE COPOLYMERS
    JANIETZ, S
    HAHN, M
    JAEGER, W
    ACTA POLYMERICA, 1992, 43 (04) : 230 - 234
  • [22] KINETICS OF THE FREE-RADICAL EMULSION POLYMERIZATION OF VINYL-CHLORIDE
    CAPEK, I
    PHYSICAL PROPERTIES OF POLYMERS, 1995, 120 : 135 - 205
  • [23] THEORY OF COMPARTMENTALIZED FREE-RADICAL POLYMERIZATION REACTIONS .5.
    BIRTWISTLE, DT
    BLACKLEY, DC
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 : 1351 - 1358
  • [24] Generation of a carbon dots/ammonium persulfate redox initiator couple for free radical frontal polymerization
    Du, Xiang-Yun
    Shen, Juncai
    Zhang, Jing
    Ling, Luting
    Wang, Cai-Feng
    Chen, Su
    POLYMER CHEMISTRY, 2018, 9 (04) : 420 - 427
  • [25] Kinetic investigations of photoinitiated free-radical polymerization of diallyldimethylammonium chloride.
    Lester, CL
    Guymon, CA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U445 - U445
  • [26] A comprehensive kinetic model for the free-radical polymerization of vinyl chloride in the presence of monofunctional and bifunctional initiators
    Krallis, A
    Kotoulas, C
    Papadopoulos, S
    Kiparissides, C
    Bousquet, J
    Bonardi, C
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (20) : 6382 - 6399
  • [27] KINETICS OF FREE-RADICAL POLYMERIZATION OF STYRENE AND O-HALOGENOSTYRENES AT LOW INITIATOR CONCENTRATIONS
    OLAJ, OF
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1968, 7 (05) : 397 - &
  • [28] New Insights on the Kinetics of Persulfate-Initiated Itaconic Acid Free-Radical Polymerization
    Herrera-Ordonez, Jorge
    MACROMOLECULAR REACTION ENGINEERING, 2023, 17 (05)
  • [29] KINETICS OF FREE-RADICAL POLYMERIZATION OF N,N-DIMETHYL-N,N-DIALLYL-AMMONIUMCHLORIDE IN CONCENTRATED AQUEOUS-SOLUTION
    TOPCIEV, DA
    MALKANDUEV, JA
    KORSAK, JV
    MIKITAEV, AK
    KABANOV, VA
    ACTA POLYMERICA, 1985, 36 (07) : 372 - 374
  • [30] KINETICS OF FREE-RADICAL POLYMERIZATION OF P-VINYLBENZYL METHYL ETHER - CROSSLINKING BY INITIATOR FREE RADICALS
    SYMCOX, RO
    COTMAN, JD
    JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1967, 5 (6PA1): : 1165 - &
12345