CYCLOPENTADIENYL RING METHYLATION AND ITS EFFECT ON SI-H BOND ACTIVATION IN (ETA-5-C5H5-N(CH3)N)MN(CO)2HSIH(C6H5)2 (N = 0, 1, 5) COMPLEXES

被引：20

作者：

LICHTENBERGER, DL

RAICHAUDHURI, A

机构：

[1] Laboratory for Electron Spectroscopy and Surface Analysis Department of Chemistry, University of Arizona Tucson

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 05期

关键词：

D O I：

10.1021/om00119a047

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The He I photoelectron spectra of (η5-C5H5)Mn(CO)2HSiHPh2, (η5-C5H4CH3)Mn(CO)2HSiHPh2, and (η5-C5(CH3)5)Mn(CO)2HSiHPh2 (Ph is C6H5) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes. © 1990, American Chemical Society. All rights reserved.

引用

页码：1686 / 1690

页数：5

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