SYNTHESIS OF A NOVEL BIDENTATE COMPLEX OF ETA-5-C5H4CH2CH(CH3)N(CH3)(C3H5)MN(CO)2

被引：51

作者：

WANG, TF

LEE, TY

WEN, YS

LIU, LK

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang, Taipei

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 403卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86482-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of the half-sandwich manganese tricarbonyl complex eta-5-C5H4CH2CH(CH3)NH(CH3)-Mn(CO)3, which itself contained a secondary amine branch on the cyclopentadienyl group, to give bidentate complex, eta-5-C5H4CH2CH(CH3) activated NHCH3Mn(CO)2. Deprotonation followed by allylation gave N-allylation compound, eta-5-C5H4CH2CH(CH3) activated N(CH3)(C3H5) Mn(CO)2, which was unequivocally identified by spectroscopic and X-ray diffraction studies.

引用

页码：353 / 358

页数：6

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