SYNTHESIS OF A NOVEL BIDENTATE COMPLEX OF ETA-5-C5H4CH2CH(CH3)N(CH3)(C3H5)MN(CO)2

被引：51

作者：

WANG, TF

LEE, TY

WEN, YS

LIU, LK

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang, Taipei

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 403卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86482-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of the half-sandwich manganese tricarbonyl complex eta-5-C5H4CH2CH(CH3)NH(CH3)-Mn(CO)3, which itself contained a secondary amine branch on the cyclopentadienyl group, to give bidentate complex, eta-5-C5H4CH2CH(CH3) activated NHCH3Mn(CO)2. Deprotonation followed by allylation gave N-allylation compound, eta-5-C5H4CH2CH(CH3) activated N(CH3)(C3H5) Mn(CO)2, which was unequivocally identified by spectroscopic and X-ray diffraction studies.

引用

页码：353 / 358

页数：6

共 50 条

[21] VIBRATIONAL SPECTRA OF C(OC2H5) (CH3)2 C(OC2H5)2 (CH3)3COC2H5 AND (CH3)3SIOC2H5 INFRARED ABSORPTION
ARBUZOVA, VA
KOVALEV, IF
TIKHOMIR.EN
VORONKOV, MG
ZHAGATA, LA
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII FIZIKA, 1968, (07): : 111 - &
[22] SYNTHESES AND REACTIONS OF THE CYCLOPENTADIENYL-DICARBONYL METHYL MANGANESE COMPLEXES [C5H5MN(CO)2(CH3)]- AND [C5H5MN(CO)2(CH3)2]
SELLMANN, D
KLOSTERMANN, P
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1983, 38 (11): : 1497 - 1500
[23] REDUCTIVE CARBONYLATION OF MN(CO)5(CH3) AND (ETA-5--C5H5)FE(CO)2(CH3) TO PRODUCE HYDROCARBONS AND OXYGEN-CONTAINING PRODUCTS
STIMSON, RE
SHRIVER, DF
ORGANOMETALLICS, 1982, 1 (06) : 787 - 793
[24] ON THE ABSOLUTE-CONFIGURATION OF ORGANO-METALLIC COMPOUNDS .8. A COMPARISON OF THE STRUCTURAL CHARACTERISTICS OF RACEMIC AND OF(-)578-(ETA-5-C5H5)MO(CO)2SC(CH3)NR WITH R = CH[CH(CH3)2](C6H5) AND (S)-CH[CH(CH3)2](C6H5)
REISNER, GM
BERNAL, I
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 220 (01) : 55 - 73
[25] Unimolecular reactivity of organotrifluoroborate anions, RBF3-, and their alkali metal cluster ions, M(RBF3)2- (M = Na, K; R = CH3, CH3CH2, CH3(CH2)3, CH3(CH2)5, c-C3H5, C6H5, C6H5CH2, CH2CHCH2, CH2CH, C6H5CO)
Bathie, Fiona L. B.
Bowen, Chris J.
Hutton, Craig A.
O'Hair, Richard A. J.
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2018, 32 (13) : 1045 - 1052
[26] THE REACTIONS OF (ETA-1-C5H5)RE(CO) (NO) (CH3) [P(CH3)3]2 WITH CARBON-MONOXIDE AND TRIMETHYLPHOSPHINE
CASEY, CP
OCONNOR, JM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 83 - INOR
[27] Ortho-mercurated [(N-methyl-N-arylaminolmethyl)ferrocenes] and their transpalladation.: Crystal structures of [(η5-C5H5)Fe{η5-C5H3 5H3(HgCl)CH2N(CH3)C6H4OCH3-4}]2 [(η5-C5H5)Fe{η5-C5H3(HgCl)CH2N(CH3)C6H4Cl-3] and [(η5 -C5H4HgCl)Fe{η5-C5H4CH2N(CH3)C6H4Cl-4]
Wang, Hong-Xing
Li, Ying-He
Wu, Hong-Fei
Gao, Ren-Qing
Geng, Feng-Ying
Yang, Xiao-Li
Wan, Li
Jin, Rong
Cui, Xiu-Ling
Wu, Yang-He
POLYHEDRON, 2006, 25 (17) : 3305 - 3311
[28] Organometallic building blocks for crystal engineering.: Synthesis, structure and hydrogen bonding interactions in [Fe(η5-C5H4-CH2(CH3)OH)2], [Fe(η5-C5H3(CH3)COOH)2], [Fe(η5-C5H4CH(CH3)NH(η5-C5H4CH(CH3))] and in the diaminecyclohexane salt [Fe(η5-C5H4COO)2]2- [(1S,2S)-(NH3)2C6H10]2+•2[H2O]
Braga, D
Maini, L
Paganelli, F
Tagliavini, E
Casolari, S
Grepioni, F
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 609 - 615
[29] AMPHOTERIC LIGANDS .4. REACTIONS OF HMN(CO)5 WITH (ALUMINOAMINO)PHOSPHINE LIGANDS - STRUCTURE OF (CO)3MN[CHOAL(CH3)2N(C(CH3)3)P(C6H5)2]-[P(C6H5)2N(C(CH3)3)AL(HCH2)(CH3)]
GRIMMETT, DL
LABINGER, JA
BONFIGLIO, JN
MASUO, ST
SHEARIN, E
MILLER, JS
ORGANOMETALLICS, 1983, 2 (10) : 1325 - 1332
[30] Measurement of the cage effect in the photolysis of the (eta(5)-C5H4(CH2)(2)N(H)C(O)(CH2)(3)CH3)(2)Mo-2(CO)(6) complex
Lindfors, BE
Nieckarz, GF
Tyler, DR
Glenn, AG
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1996, 94 (2-3) : 101 - 105

← 1 2 3 4 5 →