Bis(mu-hydroxido-kappa O-2:O)bis[bis(5-carboxypyridine-2-carboxylato-kappa N-2,O-2)iron(III)] dihydrate

被引：0
|
作者：
Cao, Wenhai [1 ]
机构：
[1] Qinghai HuangHe Hydropower Dev Co Ltd, New Energy Branch, Xining 810008, Qinghai, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813029449
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complete binuclear complex in [Fe-2(C7H4NO4)(4)(OH)(2)]center dot 2H(2)O, is generated by the application twofold symmetry. The Fe-III atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-dicarboxylato ligands, forming a distorted octahedral geometry. The Fe center dot center dot center dot Fe separation within the dinuclear complex is 3.0657 (4) angstrom. In the crystal, O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen-bonding interactions connect the molecules into a three-dimensional supramolecular network.
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页码：M625 / +
页数：9
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