COLIQUEFACTION OF COAL AND NEWSPRINT-DERIVED LIGNIN

被引:18
|
作者
AKASH, BA [1 ]
MUCHMORE, CB [1 ]
LALVANI, SB [1 ]
机构
[1] SO ILLINOIS UNIV,DEPT MECH ENGN & ENERGY PROCESSES,CARBONDALE,IL 62901
关键词
D O I
10.1016/0378-3820(94)90016-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
When lignin derived from newsprint is coliquefied with Illinois coal in tetralin under mild reaction conditions (initial hydrogen pressure of 1.07 MPa), up to 90% enhancement in coal conversion is observed. The enhancement in coal conversion is a function of liquefaction temperature. It increases from 50 to 90% as the temperature is increased from 300-degrees-C to 325-degrees-C; however, with a further increase in temperature, the enhancement declines. This behavior is explained in terms of reaction chemistry that postulates that intermediates formed during lignin depolymerization react with coal via a parallel coal depolymerization pathway. The quality of liquid products was assessed by examining the boiling point fraction data. Data clearly show synergism in terms of product quality when lignin is added to coal during depolymerization.
引用
收藏
页码:203 / 210
页数:8
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