Electrochemical Impedance Spectroscopy and Determination of the Internal Resistance as a Way to Estimate Lead-Acid Batteries Condition

被引：14

作者：

Majchrzycki, Wlodzimierz ^{[1
]}

Jankowska, Ewa ^{[1
]}

Baraniak, Marek ^{[2
]}

Handzlik, Piotr ^{[3
]}

Samborski, Robert ^{[4
]}

机构：

[1] Inst Nonferrous Met, Div Poznan Cent Lab Batteries & Cells, Forteczna 12, PL-61362 Poznan, Poland

[2] Poznan Univ Tech, Fac Chem Technol, Inst Chem & Tech Electrochem, Berdychowo 4, PL-60965 Poznan, Poland

[3] AGH Univ Sci & Technol, Fac Nonferrous Met, Dept Phys Chem & Met Nonferrous Met, Mickiewicza 30, PL-30059 Krakow, Poland

[4] Natl Inst Telecommun, Szachowa 1, PL-04894 Warsaw, Poland

来源：

BATTERIES-BASEL | 2018年 / 4卷 / 04期

关键词：

PCL-effect; stationary lead acid battery; state of health (SoH); internal resistance; electrochemical impedance spectroscopy (EIS);

D O I：

10.3390/batteries4040070

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Attempts have been made to find the best procedure for the detection of premature battery capacity loss (the so called "PCL") in AGM-VRLA 48 V batteries operating in telecommunication systems. However, recorded changes in internal resistance and potential did not give clear indications of the beginning of the PCL effect. The obtained correlation between internal resistance and potential derived from used batteries does not show the expected trend in measured parameters. It seems that the application of Electrochemical Impedance Spectroscopy (EIS), which is a faster and non-destructive method, may solve this problem. It is demonstrated that the change in internal resistance (which is an indicator of the state of health (SoH)) can be determined from EIS spectra during continuous operation of 12 V monoblocks in a backup power source of a base transceiver station (BTS).

引用

页数：13

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