OXOVANADIUM(V) AND OXOVANADIUM(IV) ORGANOMETALLIC COMPOUNDS FROM DIRECT OXIDATION OF THE CORRESPONDING VANADIUM(III) PRECURSORS - THE X-RAY STRUCTURE OF TRIS-MESITYL OXOVANADIUM(V)

被引:32
|
作者
RUIZ, J
VIVANCO, M
FLORIANI, C
CHIESIVILLA, A
GUASTINI, C
机构
[1] UNIV LAUSANNE,CHIM SECT,PL CHATEAU 3,CH-1005 LAUSANNE,SWITZERLAND
[2] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,IST STRUTTURIST CHIM,I-43100 PARMA,ITALY
关键词
D O I
10.1039/c39910000762
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organometallic derivatives of vanadium(III) VL3(1)(L1 = Mes = 2,4,6-Me3C6H2), VL3(2)[L2 = eta-2-C(Mes) = NBu(t)], VL3(3) [L3 = O-C(Mes) = NPh] have been converted either by epoxides or dioxygen to the corresponding oxovanadium(V) and oxovanadium(IV) complexes.
引用
收藏
页码:762 / 764
页数:3
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