ASYMMETRIC-SYNTHESIS OF 3,3-DIPHENYL-2-METHYLALANINE, A NEW UNUSUAL ALPHA-AMINO-ACID FOR PEPTIDES OF BIOLOGICAL INTEREST

被引：31

作者：

CATIVIELA, C

DIAZDEVILLEGAS, MD

GALVEZ, JA

机构：

[1] Instituto de Ciencia de Materiales de Aragón, Departamento de Química Orgánica, Univesidad de Zaragoza-CSIC

来源：

TETRAHEDRON | 1994年 / 50卷 / 32期

关键词：

D O I：

10.1016/S0040-4020(01)85549-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A strategy of highly stereoselective enolate trapping of lithium (1S,1R,4R)-10-dicyclohexylsulfamoylisobornyl-2-cyano-3,3-diphenylpropanoate combined with the appropriate rearrangement process allows the asymmetric synthesis of a novel a-methyl amino acid derived from 3,3-diphenylalanine (Dip).

引用

页码：9837 / 9846

页数：10

共 50 条

[11] CYCLIC-DERIVATIVES OF 3,3-DIPHENYLALANINE (DIP) (II), NOVEL ALPHA-AMINO-ACIDS FOR PEPTIDES OF BIOLOGICAL INTEREST
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