NITRATION OF 2,7-DI-TERT-BUTYL-TRANS-10B,10C-DIMETHYL-10B,10C-DIHYDROPYRENE - ELECTROCHEMICAL INQUIRY INTO INTERACTION BETWEEN SUBSTITUENTS IN A HUCKEL 4N+2 SYSTEM

被引:9
|
作者
YAMATO, T
FUJITA, K
KAMIMURA, H
TASHIRO, M
FRY, AJ
SIMON, J
OCHTERSKI, J
机构
[1] KYUSHU UNIV,INST ADV MAT STUDY,KASUGA,FUKUOKA 816,JAPAN
[2] WESLEYAN UNIV,DEPT CHEM,MIDDLETOWN,CT 06459
基金
美国国家科学基金会;
关键词
ELECTROCHEMISTRY; NON-BENZENOID; NITRO COMPOUNDS; NITRATION; X-RAY CRYSTALLOGRAPHY;
D O I
10.1016/0040-4020(95)00589-Z
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A revised structure is reported for the product of dinitration of 2,7-di-t-butyl-10b,10c-dimethyl-10b,10c-dihydropyrene. The novel ortho-dinitro orientation and the electrochemical behavior of the mono and dinitro compounds are compared with the corresponding benzenoid substances.
引用
收藏
页码:9851 / 9858
页数:8
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