REACTIONS OF THE MO=S BOND IN THE [(CP)MO(O)(MU-S)2MO(O)(S)]- COMPLEX WITH SO2 - AN H-1-NMR STUDY AND THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(CP)MO(O)(MU-S)2MO(O)(L)]- COMPLEXES CONTAINING SO2-DERIVED SULFITE, THIOSULFATE, AND SULFATE BIDENTATE CHELATING LIGANDS

被引：16

作者：

KIM, CG ^{[1
]}

COUCOUVANIS, D ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 10期

关键词：

D O I：

10.1021/ic00062a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the Mo=S unit in the [(Cp)Mo(O)(mu-S)2Mo(O)(S)]- complex with SO2 at various temperatures give various products of the type [(CP)Mo(O)(mu-S)2Mo(O)(L)]- (L = SO32-, S2O32- , and SO42-). A H-1-NMR study of these reactions indicates that the final products isolated and structurally characterized are derivatives of the unstable [(Cp)Mo(O)(mu-S)2Mo(O)(S2O2)]-complex that forms initially by SO2 addition to the Mo=S unit and undergoes further reactions with SO2.

引用

页码：1881 / 1882

页数：2

共 50 条

[21] Reduction of [CP2*Mo2O5] by thioglycolic acid in an aqueous medium:: Synthesis and structure of [{Cp*Mo(μ-SCH2COO)}2(μ-S)]
Demirhan, F
Taban, G
Baya, M
Dinoi, C
Daran, JC
Poli, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (04) : 648 - 654
[22] REACTIVITY OF A BRIDGING SULFHYDRYL LIGAND, S-ALKYLATION OF [MO(NC6H4CH3)(S2P(OC2H5)2)]2(MU-S)(MU-SH)(MU-O2CCF3), AND STRUCTURE OF [MO(NC6H4CH3)(S2P(OC2H5)2)]2(MU-S)(MU-SCH3)(MU-O2CCF3)
NOBLE, ME
FOLTING, K
HUFFMAN, JC
WENTWORTH, RAD
INORGANIC CHEMISTRY, 1984, 23 (05) : 631 - 634
[23] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE DIMERIC TETRAIMIDO COMPLEX [MO(N-O-TOLYL)(ETA(2)-S(2)CNET(2))(MU-N-O-TOLYL)](2)
FORSTER, GD
HOGARTH, GE
POLYHEDRON, 1995, 14 (10) : 1401 - 1403
[24] DISULFUR-BRIDGED COMPLEXES OF MOLYBDENUM - CRYSTAL-STRUCTURE OF THE DIMOLYBDENUM(IV) COMPLEX [(MOCL3(C4H8S))2(MU-S2)(MU-C4H8S)] AND OF THE MO(IV)MO(V) COMPLEX [(ME2S)2CL2MO(MU-S2)(MU-S)MOCL3(SME2)]
HUGHES, DL
LANE, JD
RICHARDS, RL
SHORTMAN, C
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (05): : 621 - 626
[25] TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .11. MOLYBDENUM OXO COMPLEXES OF THE TYPE [MO(IV)(O)(S2)2], [MO(VI)(O)2(S4)], [MO(IV)(O)(S4)] AND [MO(IV)(O)(S5)] WITH BIDENTATE, TETRADENTATE AND PENTADENTATE THIOETHER-THIOLATE LIGANDS (SX = MULTIDENTATE THIOETHER-THIOLATE LIGAND)
SELLMANN, D
ZAPF, L
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1985, 40 (03): : 368 - 372
[26] SYNTHESIS OF THIOMOLYBDENYL COMPLEXES WITH [MO2(S)2(O)2]2+ CORES AND SUBSTITUTIONALLY LABILE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF THE [MO2O2S4(DMF)3] COMPLEX
COUCOUVANIS, D
TOUPADAKIS, A
HADJIKYRIACOU, A
INORGANIC CHEMISTRY, 1988, 27 (19) : 3272 - 3273
[27] PARTIAL HYDROLYSIS OF [MO(NR)(MU-3-S)(S2P(OR')2)]4 AND MOLECULAR-STRUCTURES OF MO2O(NC6H4CH3)(MU-S)2(S2P(OCH3)2)2 AND CUBANE-LIKE [MO2O(NC6H5)(MU-3-S)2(S2P(OC2H5)2)2]2
NOBLE, ME
FOLTING, K
HUFFMAN, JC
WENTWORTH, RAD
INORGANIC CHEMISTRY, 1983, 22 (24) : 3671 - 3676
[28] CARBON-SULFUR BOND FORMATION THROUGH THE REACTION OF SULFUR-BRIDGED MOLYBDENUM CLUSTERS WITH ACETYLENE - X-RAY STRUCTURES OF [MO3(MU-3-S)(MU-O)(MU-S)2(H2O)9]-(CH3C6H4SO3)4-CENTER-DOT-7H2O AND [MO3(MU-3-S)(MU-O)(MU-3-S2C2H2)(H2O)9](CH3C6H4SO3)4-CENTER-DOT-7H2O
SHIBAHARA, T
SAKANE, G
MOCHIDA, S
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) : 10408 - 10409
[29] DIMOLYBDENUM OXO-IMIDO COMPLEXES - REACTIVITY OF [(MEC5H4)2MO2O2(MU-O)(MU-NPH)] AND CRYSTAL-STRUCTURE OF [(MEC5H4)2MO2O(S)(MU-O)(MU-NPH)]
FLETCHER, J
HOGARTH, G
TOCHER, DA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 405 (02) : 207 - 215
[30] The thermal decomposition of S2O forming SO2, S3, S4 and S5O -: An ab initio MO study
Steudel, R
Steudel, Y
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (17) : 3513 - 3521

← 1 2 3 4 5 →