SYNTHESIS, CHARACTERIZATION AND THE CRYSTAL-STRUCTURE OF A CIS-DIOXOVANADIUM(V) COMPLEX OF A TRIDENTATE SCHIFF-BASE LIGAND

被引：9

作者：

LIU, HX ^{[1
]}

WANG, W ^{[1
]}

WANG, X ^{[1
]}

TAN, MY ^{[1
]}

机构：

[1] LANZHOU UNIV,CTR INSTRUMENTAL ANAL & RES,LANZHOU 730000,PEOPLES R CHINA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1994年 / 33卷 / 04期

关键词：

CIS-DIOXOVANADIUM; SCHIFF BASE; TERDENTATE; CRYSTAL STRUCTURE;

D O I：

10.1080/00958979408024294

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex, [VO2{C6H5C(O)CHC(CH3)NNC(O)CH2(NC5H5)}].C2H5OH, was synthesized and characterized by elemental analysis and spectroscopy. Yellow crystals of the complex are monoclinic, space group P2(1)/a with a = 10.690(2), b = 16.008(3), c = 13.164(4)Angstrom, beta = 107.03(2)degrees, V = 2153.9(18)Angstrom(3), F(000) = 880 and Dc = 1.305 g cm(-3) for Z = 4. X-ray structure analysis shows that the vanadium coordination number is five and the coordination polyhedron is a distorted trigonal bipyramid.

引用

页码：347 / 352

页数：6

共 50 条

[21] Synthesis and Crystal Structure of a Novel Binuclear Cu(Ⅱ) Complex with Tetradentate Schiff-base Ligand
ZHAO HaiYana b QIU XiaoHanga TONG XiaoLana SHEN PanWena a Department of Chemistry Nankai University Tianjin China b College of Science Hebei University of Science and Technology Shijiazhuang China
结构化学, 2006, (09) : 1095 - 1099
[22] Synthesis and Crystal Structure of a Novel Binuclear Cu(Ⅱ) Complex with Tetradentate Schiff-base Ligand
ZHAO Hai-Yana
Chinese Journal of Structural Chemistry, 2006, (09) : 1095 - 1099
[23] Synthesis, Crystal Structure and Nonlinear Optical Properties of Nickel(Ⅱ) Complex with Schiff-base Ligand
XUE Zhao-Minga ZHANG Xuan-Juna TIAN Yu-Penga
结构化学, 2003, (03) : 265 - 269
[24] Synthesis and electrochemical characterization of a tridentate Schiff-base ligated Fe(II) complex
Martin, Daniel J.
McCarthy, Brian D.
Piro, Nicholas A.
Dempsey, Jillian L.
POLYHEDRON, 2016, 114 : 200 - 204
[25] STRUCTURAL AND SPECTROSCOPIC CHARACTERIZATION OF DIOXOVANADIUM(V) COMPLEXES WITH ASYMMETRIC SCHIFF-BASE LIGANDS
ROOT, CA
HOESCHELE, JD
CORNMAN, CR
KAMPF, JW
PECORARO, VL
INORGANIC CHEMISTRY, 1993, 32 (18) : 3855 - 3861
[26] THE PREPARATION AND CRYSTAL-STRUCTURE OF A DIOXOURANIUM(VI) AND OF AN OXOVANADIUM(IV) COMPLEX WITH A HEXADENTATE, COMPARTMENTAL SCHIFF-BASE LIGAND
BAILEY, NA
FENTON, DE
PHILLIPS, CA
CASELLATO, U
TAMBURINI, S
VIGATO, PA
GRAZIANI, R
INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1985, 109 (02): : 91 - 98
[27] Synthesis and Crystal Structure of Copper(Ⅱ) Compound with Didentate Schiff-base Ligand
YI Long DING Bin CHENG Peng② (Department of Chemistry
结构化学, 2004, (01) : 25 - 28
[28] PREPARATION, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF A BINUCLEAR THORIUM(IV) COMPLEX WITH A PENTADENTATE COMPARTMENTAL SCHIFF-BASE
CASELLATO, U
GUERRIERO, P
TAMBURINI, S
VIGATO, PA
GRAZIANI, R
INORGANICA CHIMICA ACTA, 1987, 134 (01) : 165 - 174
[29] Crystal structure and properties of a Cu(II) complex with the tridentate Schiff-base ligand, paeonol-(2-aminoethylpiperazine)
Xu, Rui-Bo
Xu, Xing-You
Wang, Ming-Yan
Wang, Da-Qi
Yin, Ting
Xu, Guo-Xiang
Yang, Xu-Jie
Lu, Lu-De
Wang, Xin
Lei, Yong-Jun
JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (20) : 3306 - 3313
[30] Synthesis and crystal structure of a novel binuclear Cu(II) complex with tetradentate Schiff-base ligand
Zhao Hai-Yan
Qiu Xiao-Hang
Tong Xiao-Lan
Shen Pan-Wen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (09) : 1095 - 1099

← 1 2 3 4 5 →