Bis(mu(2) isopropylimido-kappa(2) N:N) bis[(eta(5) cyclopentadienyl)(ethenolato- kappa O)titanium(IV)]

被引：1
|
作者：
Haehnel, Martin [1 ]
Spannenberg, Anke [1 ]
Rosenthal, Uwe [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse E, Albert Einstein Str 29A, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536813033072
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title dinuclear half-sandwich complex, [CpTi(OCH=CH2)(mu(2)-N-iPr)](2) (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each Ti-IV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry.
引用
收藏
页码：M16 / +
页数：8
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