TEMPERATURE DEPENDENCE OF Fe-57-MOSSBAUER SPECTRA FOR A Fe-Fc(II) - Fe-tpy(II) - Fe-Fc(II) TRINUCLEAR SYSTEM

被引：0
|
作者：
Sirbu, Dumitru [1 ]
机构：
[1] Moldavian Acad Sci, Inst Chem, 3 Acad Str, MD-2028 Kishinev, Moldova
来源：
CHEMISTRY JOURNAL OF MOLDOVA | 2015年 / 10卷 / 01期
关键词：
ferrocene; terpyridine; Mossbauer; Debye temperature;
D O I：
10.19261/cjm.2015.10(1).12
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fe-57 Mossbauer spectra were recorded for 1'-terpyridine ferrocenecarboxylic acid and [bis(1'-terpyridine ferrocenecarboxylic acid) Fe(II)](2+) in the temperature range 7 - 293 K. The temperature dependence of the Quadrupole Splitting, Isomer Shift and Debye-Waller factor are discussed. The Debye temperature for the iron nuclei in the investigated compounds was determined.
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页码：84 / 88
页数：5
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