MNO THIN-FILM CATHODE FOR RECHARGEABLE MICROBATTERIES

被引：2
|
作者：
CHEN, LQ
SCHOONMAN, J
机构：
[1] Laboratory for Inorganic Chemistry, Delft University of Technology, 2628 BL Delft
来源：
SOLID STATE IONICS | 1993年 / 60卷 / 04期
关键词：
D O I：
10.1016/0167-2738(93)90002-K
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Thin films of MnO were deposited by electron beam evaporation using a MnO or MnO2 source. The thin films were characterized by X-ray and electron diffraction. The Coulomb titration curve reveals a potential plateau of 2.9 V over the composition range 0.05 < x < 2.0. The chemical diffusion coefficient of lithium in thin films at 15-degrees-C is 2.7 x 10(-14) cm2/s for 0 < x < 0.01 and 2.2 x 10(-11) cm2/s for 0.02 < x < 0.06. Good reversibility for lithium insertion and extraction is demonstrated by cyclic voltammetry.
引用
收藏
页码：227 / 231
页数：5
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