STRUCTURE OF [BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE-P,P,P]CARBONYL-(PHENYLTHIOLATO)COBALT(I), [CO(PH2PCH2CH2P(PH)CH2CH2PPH2)(SPH)(CO)

被引：5
|
作者：
WEI, GW
HUANG, ZY
LEI, XJ
CAO, R
JIANG, FL
HONG, MC
LIU, HQ
机构：
[1] CHINESE ACAD SCI,FUZHOU LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA
[2] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUJIAN 350002,PEOPLES R CHINA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷
关键词：
D O I：
10.1107/S0108270192003731
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[CO(C34H33P3)(C6H5S)(CO)], M(r) = 730.68, monoclinic, P2(1), a = 11.163 (2), b = 15.499 (3), c = 10.427 (2) angstrom, beta = 94.18 (3)-degrees, V = 1799.34 (93) angstrom3, Z = 2, D(x) = 1.349 g cm-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = 6.928 cm-1, F(000) = 760, T = 296 K, final R = 0.043 for 1866 observed unique reflections. The compound is an asymmetric molecule with a five-coordinate Co atom. The Co-S, Co-C and average value of Co-P bond distances are 2.302 (3), 1.741 (9) and 2.160 (3) angstrom, respectively.
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页码：2130 / 2132
页数：3
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