THE EFFECT OF IRON IONS ON THE DEFECT STRUCTURE OF LITHIUM-NIOBATE CRYSTALS GROWN FROM K2O CONTAINING MELTS

被引:32
|
作者
MALOVICHKO, GI [1 ]
GRACHEV, VG [1 ]
SCHIRMER, OF [1 ]
机构
[1] UNIV OSNABRUCK, FACHBEREICH PHYS, D-49069 OSNABRUCK, GERMANY
关键词
D O I
10.1016/0038-1098(94)90681-5
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The most narrow ESR linewidths possible for Fe-Li(3+) in nominally pure melts are observed in stoichiometric material obtained from growth out of melts containing K2O. We report that the addition of only 0.05 wt% Fe2O3 to the melt strongly increases the linewidths, pointing to a pronounced in influence of Fe on the defect structure of LiNbO3. Optical absorption studies show that Fe-Li(2+) exists in such crystals in higher concentrations than in conventional LiNbO3 even before reduction. This is attributed to the decreased content of intrinsic compensating defects, caused by K2O growth.
引用
收藏
页码:195 / 198
页数:4
相关论文
共 50 条
  • [31] Effect of K2O on structure-property relationships and phase transformations in Li2O-SiO2 glasses
    Fernandes, Hugo R.
    Tulyaganov, Dilshat U.
    Goel, Ashutosh
    Ferreira, Jose M. F.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (02) : 291 - 298
  • [32] Defect structure characteristics in near-stoichiometric In:LiNbO3 single crystals grown by K2O-flux method
    Fang, Shuangquan
    Han, Zhaoxiang
    Qiao, Yingjie
    Liu, Yingying
    Jia, Qi
    CRYSTAL RESEARCH AND TECHNOLOGY, 2009, 44 (11) : 1211 - 1214
  • [33] K2O effect on the crystal structure and crystallization of fresnoite in BaO-TiO2-SiO2 glasses
    Lee, Hoi Kwan
    Kang, Won Ho
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2007, 8 (01): : 22 - 27
  • [34] Effect of K2O:Al2O3 Ratio on Crystallization Phenomena and Microstructure of Lithium Silicate Glass-Ceramics
    Kolay, Santa
    Bhargava, Parag
    TRANSACTIONS OF THE INDIAN CERAMIC SOCIETY, 2021, 80 (04) : 242 - 250
  • [35] Effect of Ca/K replacement on the atomic structure of P2O5–K2O–CaO glasses: A molecular dynamics study
    Bushra Al-Hasni
    Indian Journal of Physics, 2024, 98 : 1583 - 1592
  • [36] SOLUBILITIES OF SN IN IN2O3 AND OF IN IN SNO2 CRYSTALS GROWN FROM SN-IN MELTS
    FRANK, G
    BROCK, L
    BAUSEN, HD
    JOURNAL OF CRYSTAL GROWTH, 1976, 36 (01) : 179 - 180
  • [37] GROWTH BANDS IN IRON-GARNET SINGLE-CRYSTALS GROWN FROM SOLUTIONS IN MELTS OF THE BAO-B2O3 SYSTEM
    BEZMATERNYKH, LN
    SOKOLOVA, NA
    TEMEROV, VL
    INORGANIC MATERIALS, 1983, 19 (10) : 1564 - 1566
  • [38] Potassium lithium niobate:: Single-phase domain boundary in the 30 mol% K2O isopleth of the ternary system Li2O-K2O-Nb2O5 and characterization of single-crystal fibers
    Ferriol, M
    Boulon, G
    MATERIALS RESEARCH BULLETIN, 1999, 34 (04) : 533 - 543
  • [39] CRYSTALLIZATION MECHANISM OF ZEOLITE-BETA FROM (TEA)2O, NA2O AND K2O CONTAINING ALUMINOSILICATE GELS
    PEREZPARIENTE, J
    MARTENS, JA
    JACOBS, PA
    APPLIED CATALYSIS, 1987, 31 (01): : 35 - 64
  • [40] Influence of Fe2O3-FeS on the structure of iron-containing clusters in aluminosilicate melts
    Xia, Baoliang
    Jiao, Facun
    Mao, Lirui
    Zhang, Yuanchun
    Xie, Ying
    Li, Hanxu
    ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2023, 18 (04)