MALONAMIDES AS NEW EXTRACTANTS FOR NUCLEAR WASTE SOLUTIONS

被引:237
|
作者
CUILLERDIER, C [1 ]
MUSIKAS, C [1 ]
HOEL, P [1 ]
NIGOND, L [1 ]
VITART, X [1 ]
机构
[1] IRDI,DERDCA,DGR,SEP,SCPR,F-92265 FONTENAY ROSES,FRANCE
关键词
D O I
10.1080/01496399108050526
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new class of extractants has been investigated: pentaalkylpropane diamides. Due to their chelating effect on metallic cations, they extract trivalent actinides such as Am3+ and Cm3+ from acidic nitrate nuclear waste solutions. These solvents are completely incinerable and do not generate large amounts of waste. A review is provided of their chemical properties, leading to the choice of the proper molecule. The results of a bench-scale experiment performed in a mixer-settler battery are presented.
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页码:1229 / 1244
页数:16
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