AROMATIC-SUBSTITUTION AND DEALKYLATION BY ALKANETELLUROLATE ANIONS

被引:2
|
作者
POTAPOV, VA
AMOSOVA, SV
PETROV, PA
机构
[1] Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk
关键词
D O I
10.1016/S0040-4039(00)79030-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Under the action of alkanetellurolate anion phenyl halides undergo aromatic substitution followed by dealkylation of the alkyl phenyl telluride thus formed. The generated benzenetellurolate anion can be either alkylated or oxidized Lo diphenyl ditelluride, or added to acetylene. Butyl methyl telluride and selenide are demethylated by methanechalcogenolate anions.
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页码:6515 / 6518
页数:4
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