ON THE PREPARATION OF 1H-PERFLUOROALKANES AND A MECHANISM FOR THE REDUCTION OF PERFLUOROALKYL IODIDES

被引：12
|
作者：
HOWELL, JL
MUZZI, BJ
RIDER, NL
ALY, EM
ABOUELMAGD, MK
机构：
[1] E.I. du Pont de Nemours, Co., Inc., Jackson Laboratory, Deepwater, NJ 08023, Chambers Works
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 01期
关键词：
1H-PERFLUOROALKANES; METHYL HYPOIODIDE; MECHANISM; REDUCTION; MASS SPECTROMETRY;
D O I：
10.1016/0022-1139(94)03176-Z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
1H-Perfluoroalkanes are prepared by sodium methoxide reduction of 1-iodoperfluoroalkanes. The experimental evidence indicates that the reaction proceeds either through a radical or a thermal mechanism. We have found that a high yield of 1H-perfluoroalkanes at complete conversion can be accomplished at atmospheric pressure using this technology.
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页码：61 / 68
页数：8
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