DETECTION OF NITROGEN-ATOMS PRODUCED BY PREDISSOCIATION OF SUPEREXCITED RYDBERG STATES OF NO

被引：32
|
作者：
FUJII, A
MORITA, N
机构：
[1] Institute for Molecular Science, Okazaki, 444, Myodaiji
来源：
CHEMICAL PHYSICS LETTERS | 1991年 / 182卷 / 3-4期
关键词：
D O I：
10.1016/0009-2614(91)80219-N
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Predissociation processes of superexcited Rydberg states (v = 1, n = 8 - 17, l = s, p and f) of the NO molecule have been investigated by detecting the fragment nitrogen atom with a resonance-enhanced multiphoton ionization (REMPI) technique. As a result, the N (2D) production predicted by theoretical calculations has been confirmed. Moreover, the unexpected generation of N (4S) has also been observed. Yields of the fragment atoms are strongly dependent on both the principal and angular momentum quantum numbers of the Rydberg electron.
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收藏
页码：304 / 309
页数：6
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