A KNUDSEN CELL MONOPOL MASS-SPECTROMETER FOR USE IN HIGH-TEMPERATURE THERMODYNAMICS

被引：10
|
作者：
VRESTAL, J
TOMISKA, J
机构：
[1] MASARYK UNIV, INST THEORET & PHYS CHEM, 61137 BRNO, CZECHOSLOVAKIA
[2] UNIV VIENNA, INST PHYS CHEM, A-1090 VIENNA, AUSTRIA
来源：
MONATSHEFTE FUR CHEMIE | 1993年 / 124卷 / 11-12期
关键词：
MASS SPECTROMETRY; THERMODYNAMICS; INSTRUMENTATION; KNUDSEN TECHNIQUE;
D O I：
10.1007/BF00810017
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A high temperature Knudsen cell was combined with a monopol mass spectrometer model MX 7304 with the ion source 1560014-T01 (Electron, Ukraine) despite the fact that these apparates have been designed for application in organic chemistry only. Relatively simple engineering details, as well as an extremely careful electrical optimisation of the operating conditions yielded a powerful measuring device for application in high temperature thermodynamics. Test measurements as well as the determination of the second law heats of sublimation of solid Fc, Co, Ni, Cu and Cr proved the efficiency of the new device.
引用
收藏
页码：1099 / 1106
页数：8
相关论文
共 50 条
  • [21] HIGH-TEMPERATURE KNUDSEN CELL WITH GRAPHITE HEATING ELEMENT
    TAYLOR, AP
    YANG, K
    SCHOWALTER, LJ
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1991, 9 (06): : 3181 - 3182
  • [22] A RECONSTRUCTED MASS-SPECTROMETER IN COMBINATION WITH A KNUDSEN CELL FOR THERMODYNAMIC INVESTIGATIONS AT HIGH-TEMPERATURES - THE SYSTEM IRON(I) NICKEL(I)
    TOMISKA, J
    ZEITSCHRIFT FUR METALLKUNDE, 1985, 76 (08): : 532 - 537
  • [23] TWIN-CHAMBER KNUDSEN EFFUSION CELL MASS-SPECTROMETER FOR ALLOY THERMODYNAMIC STUDIES .2.
    STICKNEY, MJ
    CHANDRASEKHARAIAH, MS
    GINGERICH, KA
    HIGH TEMPERATURE SCIENCE, 1989, 26 : 187 - 195
  • [24] THE HIGH-TEMPERATURE VAPORIZATION THERMODYNAMICS OF LANTHANUM AND YTTRIUM MONOPHOSPHIDES AS DETERMINED BY KNUDSEN EFFUSION
    FRANZEN, HF
    HARIHARAN, AV
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1980, 12 (10): : 975 - 984
  • [25] HIGH-RESOLUTION MASS-SPECTROMETER
    ALEXANDRU, G
    DUTESCU, N
    MOLNAR, S
    STUDII SI CERCETARI DE FIZICA, 1972, 24 (06): : 765 - +
  • [26] HIGH SENSITIVITY PROGRAMMABLE MASS-SPECTROMETER
    NAKAO, F
    YAMAMOTO, T
    JAPANESE JOURNAL OF APPLIED PHYSICS, 1974, : 167 - 170
  • [27] A high-intensity mass-spectrometer
    Smythe, WR
    Rumbaugh, LH
    West, SS
    PHYSICAL REVIEW, 1934, 45 (03): : 0220 - 0221
  • [28] Improvements and new capabilities for the multiple Knudsen cell device used in high-temperature mass spectrometry
    Heyrman, M
    Chatillon, C
    Collas, H
    Chemin, J
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2004, 18 (02) : 163 - 174
  • [29] MEASUREMENTS OF ION-MOLECULE REACTION-RATES IN A HIGH-TEMPERATURE DRIFT TUBE - MASS-SPECTROMETER APPARATUS
    CHEN, AK
    JOHNSEN, R
    BIONDI, MA
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1978, 23 (02): : 157 - 157
  • [30] Development of the High-Temperature Knudsen Effusion Mass Spectrometry in the Nordic Countries
    Stolyarova, Valentina L.
    Shilov, Andrey L.
    Vorozhtcov, Viktor A.
    STEEL RESEARCH INTERNATIONAL, 2024,
12345