HEMIQUANTAL STUDY OF THE ISOTOPIC EXCHANGE-REACTION O-18(P-3)+(OO)-O-16-O-16((3)SIGMA(-)(G))-](OO)-O-18-O-16((3)SIGMA(-)(G))+O-16(P-3)

被引：15
|
作者：
CHAJIA, M
JACON, M
机构：
[1] Groupe de Spectrométrie Moléculaire et Atmosphérique, URA D1434, Faculté des Sciences, 51062 Reims Cedex
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 01期
关键词：
D O I：
10.1063/1.468180
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A hemiquantal three-dimensional calculation of the isotopic exchange reaction O-18(P-3) +(OO16)-O-16((3) Sigma(g)(-))-->(OO16)-O-18((3) Sigma(g)(-))+O-16(P-3), which plays an important part in the atmospheric ozone photochemistry, is presented. The method gives an estimation of the lifetime of the activated complex which may be formed during the collision. Reaction scattering cross sections and rate constants are determined. A comparison with previous classical calculations and experimental results are made.
引用
收藏
页码：271 / 282
页数：12
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