HYDROGENATION OF HEPTALDEHYDE TO HEPTYL ALCOHOL WITH NICKEL-CATALYSTS

被引：2

作者：

VIJAYALAKSHMI, P ^{[1
]}

SUBBARAO, R ^{[1
]}

机构：

[1] INDIAN INST CHEM TECHNOL,CSIR,DIV OILS & FATS,HYDERABAD 500007,INDIA

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1993年 / 70卷 / 04期

关键词：

HEPTALDEHYDE; HEPTYL ALCOHOL; HYDROGENATION; RANEY NICKEL;

D O I：

10.1007/BF02552720

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Hydrogenation of heptaldehyde to heptyl alcohol was studied with W2 Raney nickel catalyst, prepared in the laboratory, commercial Raney nickel catalyst and Rufert nickel catalyst by varying temperature, catalyst concentration, hydrogen pressure and reaction time. The products were analyzed by gas-liquid chromatography on SE-30 column. The optimum conditions found for quantitative conversion (99.6%) of heptaldehyde to heptyl alcohol were: temperature, 100-degrees-C, W2 Raney nickel catalyst concentration, 2% based on heptaldehyde (w/w), hydrogen pressure, 145 psig and reaction time, 1 h.

引用

页码：435 / 436

页数：2

共 50 条

[41] LIQUID-PHASE STEREOSELECTIVE THYMOL HYDROGENATION OVER SUPPORTED NICKEL-CATALYSTS
ALLAKHVERDIEV, AI
KULKOVA, NV
MURZIN, DY
CATALYSIS LETTERS, 1994, 29 (1-2) : 57 - 67
[42] STEADY-STATE AND ISOTOPIC TRANSIENT KINETICS OF BENZENE HYDROGENATION ON NICKEL-CATALYSTS
MIRODATOS, C
DALMON, JA
MARTIN, GA
JOURNAL OF CATALYSIS, 1987, 105 (02) : 405 - 415
[43] PYROPHORITY ON NICKEL-CATALYSTS OF RHENIUM
SAVELOV, AI
FASMAN, AB
LYASHENKO, AI
YUSKEVICH, OI
KHODAREVA, TA
ZHURNAL FIZICHESKOI KHIMII, 1988, 62 (11): : 3102 - 3104
[44] POISONING OF NICKEL-CATALYSTS BY ARSENIC
NIELSEN, B
VILLADSEN, J
APPLIED CATALYSIS, 1984, 11 (01): : 123 - 138
[45] STUDIES ON HYDROGENATION WITH NICKEL-CATALYSTS .8. CATALYTIC PROPERTIES OF COLLOIDAL NICKEL FOR HYDROGENATION OF CARBON CARBON DOUBLE-BONDS
SAKAI, M
MINAMIDA, Y
SASAKI, K
SAKAKIBARA, Y
NIPPON KAGAKU KAISHI, 1992, (04) : 412 - 414
[46] SELECTIVE HYDROGENATION OF (-)-ALPHA-PINENE OVER NICKEL-CATALYSTS PREPARED BY ELECTROLESS DEPOSITION
KO, SH
CHOU, TC
YANG, TJ
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (02) : 457 - 467
[47] THE GAS-PHASE HYDROGENATION OF BENZENE USING PHOSPHATE-SUPPORTED NICKEL-CATALYSTS
MARCELIN, G
VOGEL, RF
SWIFT, HE
JOURNAL OF CATALYSIS, 1986, 98 (01) : 64 - 69
[48] KINETICS, ISOTOPE EFFECTS, AND MECHANISM FOR THE HYDROGENATION OF CARBON-MONOXIDE ON SUPPORTED NICKEL-CATALYSTS
MORI, T
MASUDA, H
IMAI, H
MIYAMOTO, A
BABA, S
MURAKAMI, Y
JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (14): : 2753 - 2760
[49] ENANTIOSELECTIVE HYDROGENATION OF ETHYL ACETOACETATE ON COPPER NICKEL-CATALYSTS AND EFFECT OF CATALYST PREPARATION CONDITIONS
CHERNYSHEVA, VA
ZUBAREVA, ND
KLABUNOVSKII, EI
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1984, 33 (11): : 2233 - 2234
[50] INTERPRETATION OF HYDROGEN CHEMISORPTION ON NICKEL-CATALYSTS
RICHARDSON, JT
CALE, TS
JOURNAL OF CATALYSIS, 1986, 102 (02) : 419 - 432

← 1 2 3 4 5 →