REVERSE WATER-GAS SHIFT REACTION CATALYZED BY RUTHENIUM CLUSTER ANIONS

被引：51
|
作者：
TOMINAGA, KI
SASAKI, Y
HAGIHARA, K
WATANABE, T
SAITO, M
机构：
[1] NATL INST RESOURCES & ENVIRONM, TSUKUBA, IBARAKI 305, JAPAN
[2] RES INST INNOVAT TECHNOL EARTH, CO2 FIXAT PROJECT SECT, TSUKUBA, IBARAKI 305, JAPAN
来源：
CHEMISTRY LETTERS | 1994年 / 08期
关键词：
D O I：
10.1246/cl.1994.1391
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reverse water-gas shift reaction (H-2+CO2-->CO+H2O) was homogeneously catalyzed by anionic Ru cluster in the presence of bis(triphenylphosphine)imminium chloride ([PPN]Cl). The catalytic reaction was estimated to proceed via dehydrogenation of hydride cluster, followed by coordination of CO2 and electrophilic attack of proton on its oxygen atom in the presence of chloride anion.
引用
收藏
页码：1391 / 1394
页数：4
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