KINETICS OF THE CATALYTIC HYDROCHLORINATION OF METHANOL TO METHYL-CHLORIDE

被引：16
|
作者：
BECERRA, AM [1 ]
LUNA, AEC [1 ]
ARDISSONE, DE [1 ]
PONZI, MI [1 ]
机构：
[1] UNIV NACL SAN LUIS,FAC INGN & ADM,INTEQUI,CONICET,AV 25 MAYO 384,RA-5730 VILLA MERCEDES,ARGENTINA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1992年 / 31卷 / 04期
关键词：
D O I：
10.1021/ie00004a011
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The intrinsic kinetics of the catalytic hydrochlorination of methanol to methyl chloride on gamma-Al2O3 was determined from experiments in a tubular reactor in the temperature range of 513-593 K and at atmospheric pressure, after a catalyst screening and a study of operative conditions. A large number of detailed reaction mechanisms was considered. A strategy of model discrimination and parameter estimation led to a Hougen-Watson type model with statistically significant and thermodynamically consistent parameters.
引用
收藏
页码：1040 / 1045
页数：6
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