KINETICS OF THE CATALYTIC HYDROCHLORINATION OF METHANOL TO METHYL-CHLORIDE

被引：16

作者：

BECERRA, AM ^{[1
]}

LUNA, AEC ^{[1
]}

ARDISSONE, DE ^{[1
]}

PONZI, MI ^{[1
]}

机构：

[1] UNIV NACL SAN LUIS,FAC INGN & ADM,INTEQUI,CONICET,AV 25 MAYO 384,RA-5730 VILLA MERCEDES,ARGENTINA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1992年 / 31卷 / 04期

关键词：

D O I：

10.1021/ie00004a011

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The intrinsic kinetics of the catalytic hydrochlorination of methanol to methyl chloride on gamma-Al2O3 was determined from experiments in a tubular reactor in the temperature range of 513-593 K and at atmospheric pressure, after a catalyst screening and a study of operative conditions. A large number of detailed reaction mechanisms was considered. A strategy of model discrimination and parameter estimation led to a Hougen-Watson type model with statistically significant and thermodynamically consistent parameters.

引用

页码：1040 / 1045

页数：6

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