CONDENSATION OF SCH2CH2S2- DURING THE FORMATION OF A NICKEL(II) COMPLEX CONTAINING MIXED-LIGANDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF NI(PPH3)(TPDT)

被引：11

作者：

CAO, R ^{[1
]}

LEI, XJ ^{[1
]}

HUANG, ZY ^{[1
]}

HONG, MC ^{[1
]}

LIU, HQ ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1992年 / 25卷 / 02期

关键词：

NICKEL; CONDENSATION; CRYSTAL STRUCTURE; 1,2-ETHANEDITHIOL; PHOSPHINE;

D O I：

10.1080/00958979209409748

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of NiCl2, PPh3 and Na2edt (edt2− = SCH2CH2S2−) in methanol gives rise to the cleavage of the C-S bond in edt and a new nickel(II) complex, Ni(PPh3)(tpdt) (tpdt2− = SCH2CH2SCH2CH2S2−). The complex crystallizes in the monoclinic space group P21/n with a = 9.383(4), b = 16.380(4), c = 14.177(4) Å, β = 102.75(3)°, V = 2125.2 Å3, Z = 4; Mr= 473.30; Dc= 1.479 gcm−3; F(000) = 984; μ = 12.79 cm−1. Final R is 0.052 for 2017 observed reflections. The nickel atom is four-coordinated with a distorted square-planar geometry with Ni-S distances in the range 2.150-2.180 Å and with Ni-P equal to 2.187 Å. © 1992, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：165 / 169

页数：5

共 50 条

[21] Synthesis and structure analysis of α and β forms of [12] metallacrown-6 nickel(II) complex: [Ni6(SCH2CH2CH3)12]
Xiao, Hai Lian
Jian, Fang Fang
Zhang, Ke Jie
Bulletin of the Korean Chemical Society, 2009, 30 (04) : 846 - 848
[22] Synthesis and Structure Analysis of α and β Forms of [12] Metallacrown-6 Nickel(II) Complex: [Ni6(SCH2CH2CH3)12]
Xiao, Hai Lian
Jian, Fang Fang
Zhang, Ke Jie
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2009, 30 (04): : 846 - 848
[23] ADDITION-REACTIONS AND CRYSTAL-STRUCTURE OF TRANS-CH3IR(CO)(PPH3)2
REES, WM
CHURCHILL, MR
LI, YJ
ATWOOD, JD
ORGANOMETALLICS, 1985, 4 (07) : 1162 - 1167
[24] SYNTHESIS AND CRYSTAL-STRUCTURE OF W2S4BR2(PPH3)2.C6H6
FEDIN, VP
MIRONOV, YV
VIROVETS, AV
PODBEREZSKAYA, NV
FEDOROV, VY
INORGANICA CHIMICA ACTA, 1990, 171 (02) : 199 - 203
[25] THE REACTION OF CPRU(PPH3)2+ WITH ORGANIC THIOLS - SYNTHESIS AND CHARACTERIZATION OF [CPRU(PPH3)2(RSH)]BF4 (R = BENZYL, PHENETHYL) AND THE MOLECULAR AND CRYSTAL-STRUCTURE OF [CPRU(PPH3)2(C6H5CH2CH2SH)]BF4.CH2CL2
PARK, HS
MINICK, D
DRAGANJAC, M
CORDES, AW
HALLFORD, RL
EGGLETON, G
INORGANICA CHIMICA ACTA, 1993, 204 (02) : 195 - 198
[26] Synthesis,Characterization and Crystal Structure of a Diiron Azadithiolate Complex [（μ-SCH2）2NCH2Ph]Fe2（CO）5（PPh3）
刘旭锋
肖勋文
沈梁钧
房江华
王家荣
高浩其
刘幸海
结构化学, 2011, 30 (07) : 1016 - 1020
[27] Synthesis, Characterization and Crystal Structure of a Diiron Azadithiolate Complex [(μ-SCH2)2NCH2Ph]Fe2(CO)5(PPh3)
Liu Xu-Feng
Xiao Xun-Wen
Shen Liang-Jun
Fang Jiang-Hua
Wang Jia-Rong
Gao Hao-Qi
Liu Xing-Hai
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 30 (07) : 1016 - 1020
[28] CRYSTAL AND MOLECULAR-STRUCTURE OF A THIOLATE-BRIDGED BINUCLEAR NICKEL(II) COMPLEX, [NI2(SCH(CH2CH2NH2)2)2]BR2
MIKURIYA, M
KIDA, S
MURASE, I
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (03) : 1180 - 1182
[29] CRYSTAL-STRUCTURE AND SPECTRA OF THE MIXED-LIGANDS COMPLEX 1-(2-THENOYL)-2-(2,2'-DIPYRIDYL METHYLENE)HYDRAZINO-ACETATO LEAD(II)
CHRISTIDIS, PC
TOSSIDIS, IA
HONDROUDIS, CA
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1994, 209 (12): : 975 - 978
[30] A NEW COBALT COMPLEX CONTAINING ETA-3-BONDED AND ETA-2-BONDED DIALLYL ETHER - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [CO(CH2CHCH2OCHCHCH2)-(PPH3)2]
KUSHI, Y
KURAMOTO, M
HAYASHI, Y
YAMAMOTO, T
YAMAMOTO, A
KOMIYA, S
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (18) : 1033 - 1034

← 1 2 3 4 5 →