STRUCTURAL STUDIES OF LIQUID 2-BROMOPROPANE AND 2-CHLOROPROPANE BY NEUTRON-DIFFRACTION

被引:9
|
作者
ZETTERSTROM, P [1 ]
DAHLBORG, U [1 ]
WANNBERG, A [1 ]
机构
[1] STUDSVIK NEUTRON RES LAB,NYKOPING,SWEDEN
关键词
D O I
10.1080/00268979400101701
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structures of fully deuterated liquid 2-bromopropane and 2-chloropropane have been investigated by neutron diffraction. Four different temperatures were employed and a separation of 2-bromopropane into an intramolecular and an intermolecular form factor was made. An increase in the intensity of the main peak in S-M(Q) with increasing temperature was observed. Two qualitative interpretations of this behaviour in terms of density change of the liquids are given. A comparison with the structure of liquid isopropanol is included.
引用
收藏
页码:971 / 981
页数:11
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