REACTIONS OF 2-AMINO-1-AZAAZULENES WITH DIPHENYLCYCLOPROPENONE

被引：7
|
作者：
ABE, N [1 ]
KAKEHI, A [1 ]
机构：
[1] SHINSHU UNIV,FAC ENGN,DEPT CHEM & MAT ENGN,WAKASATO,NAGANO 380,JAPAN
来源：
HETEROCYCLES | 1993年 / 36卷 / 09期
关键词：
D O I：
10.3987/COM-93-6419
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of 2-amino-1-azaazulene with diphenylcyclopropenone gave 1,2-diphenyl-1,2,3,10b-tetrahydro-4,10b-diazabenz[a]azulen-3-one, which rearranged to N-(1-azaazulen-2-yl)-alpha-cis-stylbenecarboxamide and N-(1-azaazulen-2-yl)-alpha-trans-stylbenecarboxamide by heating. Some structures of these products were determined by the X-ray structure analyses. The reaction mechanism is discussed.
引用
收藏
页码：1961 / 1964
页数：4
相关论文
共 50 条
  • [21] FACILE SYNTHESIS OF (2-BENZIMIDAZOLYL)-1-AZAAZULENES, (2-BENZOTHIAZOLYL)-1-AZAAZULENES, AND RELATED COMPOUNDS AND EVALUATION OF THEIR ANTICANCER IN VITRO ACTIVITY
    Yamauchi, Noriko
    Fujii, Hiroyuki
    Kakehi, Akikazu
    Shiro, Motoo
    Kurosawa, Masaki
    Konakahara, Takeo
    Abe, Noritaka
    HETEROCYCLES, 2008, 76 (01) : 617 - 634
  • [22] REACTION OF 2-CHLORO-1-AZAAZULENES WITH GRIGNARD-REAGENTS
    ABE, N
    HETEROCYCLES, 1976, 4 (02) : 221 - 225
  • [23] SYNTHESIS OF [POLY(2-PYRIDYL)-SUBSTITUTED]-1-AZAAZULENES
    Ariyoshi, Tornoyuki
    Noda, Tornonori
    Watarai, Satorni
    Tagashira, Shoji
    Murakami, Yoshiko
    Fujii, Hiroyuki
    Abe, Noritaka
    HETEROCYCLES, 2009, 77 (01) : 565 - 574
  • [24] REACTIONS OF DIPHENYLCYCLOPROPENONE WITH TRIVALENT PHOSPHORUS-COMPOUNDS
    HAMADA, A
    TAKIZAWA, T
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1975, 23 (11) : 2933 - 2938
  • [25] Reaction of 1-azaazulenes with benzyne
    Abe, N
    Mori, M
    Fujii, H
    JOURNAL OF CHEMICAL RESEARCH-S, 2002, (01): : 8 - 8
  • [26] REACTIONS OF TROPONE DIPHENYLCYCLOPROPENONE AND PHENALENONE WITH DIPHENYLKETENE AND BENZENESULFONYLISOCYANATE
    GOMPPER, R
    STUDENEE.A
    ELSER, W
    TETRAHEDRON LETTERS, 1968, (08) : 1019 - &
  • [27] REACTIONS OF DIPHENYLCYCLOPROPENONE WITH KETENES IN PRESENCE OF NICKEL TETRACARBONYL
    BABA, A
    OHSHIRO, Y
    AGAWA, T
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 110 (01) : 121 - 127
  • [28] Reactions of 1-amino-2-nitroguanidine with glyoxal
    Ozerova, O. Yu.
    Efimova, T. P.
    Novikova, T. A.
    Berestovitskaya, V. M.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (11) : 2583 - 2591
  • [29] Reactions of 1-amino-2-nitroguanidine with glyoxal
    O. Yu. Ozerova
    T. P. Efimova
    T. A. Novikova
    V. M. Berestovitskaya
    Russian Journal of General Chemistry, 2015, 85 : 2583 - 2591
  • [30] SYNTHESIS AND REACTIONS OF 2-AMINO-1-AZIRINES
    RENS, M
    GHOSEZ, L
    TETRAHEDRON LETTERS, 1970, (43) : 3765 - &
12345