The use of gold coating agents has been claimed to reduce residual stress in alloy‐ceramic composites. The purpose of this study was to evaluate the efficacy of gold coating agents in preventing cracking of bonded porcelain. Residual stress in alloy‐ceramic specimens could be increased by decreasing the coefficient of thermal expansion (α) of the porcelain. Vitadur‐N porcelain (jacket crown type, low α) was mixed in increasing proportions with VMK porcelain (high α) to prepare five test blends with decreasing values for α. For each test blend, α was measured by means of a vitreous silica dilatometer, and varied from 13.6 times 10−6/K to 11.0 times 10−6/K. The test blends were fused around spherical specimens of a substrate alloy, Option (α = 14.0 times 10−6/K), both with and without the use of three gold coating agents, Wilkote, Spectra‐Seal and Deck‐Gold (normal). The composite spheres were examined under 20 x magnification after 24 hours and again after eight weeks for evidence of cracking. There was no significant difference in the failure rate of the alloy‐ceramic specimens with or without any of the gold coating agents. In a bonding porcelain, α can be lowered in a controlled manner by the addition of varying amounts of jacket crown porcelain. Cracking of the ceramic coating occurred at and above an α mismatch of 1.8 times 10−6/K. Gold coating agents have an insignificant effect on residual stress in alloy‐ceramic specimens. 1990 Australian Dental Association