STRESS-RELAXATION BEHAVIOR OF LOW EPOXIDIZED POLY(STYRENE-B-BUTADIENE-B-STYRENE) TRIBLOCK COPOLYMERS

被引：6
|
作者：
WU, GW [1 ]
HSIUE, GH [1 ]
YANG, JS [1 ]
机构：
[1] NATL TSING HUA UNIV,DEPT CHEM ENGN,HSINCHU 300,TAIWAN
来源：
MATERIALS CHEMISTRY AND PHYSICS | 1994年 / 39卷 / 01期
关键词：
STRESS RELAXATION; THERMOPLASTIC ELASTOMERS; OXIRANE; TRIBLOCK COPOLYMERS; EPOXIDIZED STYRENE-BUTADIENE COPOLYMERS;
D O I：
10.1016/0254-0584(94)90127-9
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The stress relaxation properties of low epoxidized poly(styrene-b-butadiene-b-styrene) (ESBS) triblock copolymers were investigated in this study via the stress-relaxation technique. The relaxation of the ESBS copolymers depend on the temperature and oxirane content. ESBS copolymers at low oxirane contents do not completely obey the common rule that the relaxation rate decreases with increasing epoxidization. ESBS with 1.9% oxirane has the largest relaxation rate constant. The relaxation activation energies of the ESBS copolymers with 0-2.4% oxirane were calculated to be about 85 kJ mol-1. ESBS with 1.9% oxirane has the lowest number of chains in stress for relaxation.
引用
收藏
页码：29 / 33
页数：5
相关论文
共 50 条
  • [41] Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity
    Kepic, Dejan P.
    Ristic, Ivan S.
    Marinovic-Cincovic, Milena T.
    Perusko, Davor B.
    Spitalsky, Zdenko
    Pavlovic, Vladimir B.
    Budimir, Milica D.
    Siffalovic, Peter
    Dramicanin, Miroslav D.
    Micusik, Matej
    Kleinova, Angela
    Janigova, Ivica
    Markovic, Zoran M.
    Markovic, Biljana M. Todorovic
    POLYMER INTERNATIONAL, 2018, 67 (08) : 1118 - 1127
  • [42] Synthesis of poly(styrene)-b-poly(dimethylsiloxane)-b-poly(styrene) triblock copolymers by iodine transfer polymerization in miniemulsion
    Pouget, Emmanuel
    Tonnar, Jeff
    Eloy, Cedric
    Lacroix-Desmazes, Patrick
    Boutevin, Bernard
    MACROMOLECULES, 2006, 39 (18) : 6009 - 6016
  • [43] Morphological study and photo-addressing in poly(styrene-b-butadiene-b-styrene) block copolymers with az obenzene groups and polystyrene matrix: Influence of chemical bonding
    Fernandez, Raquel
    Zalakain, Inaki
    Angel Ramos, Jose
    Martin, Loli
    Mondragon, Inaki
    EUROPEAN POLYMER JOURNAL, 2011, 47 (05) : 1176 - 1185
  • [44] Semiconducting Properties of the Hybrid Film of Elastic Poly(styrene-b-butadiene-b-styrene) Block Copolymer and Semiconducting Poly(3-hexylthiophene) Nanofibers
    Goto, Takanori
    Morita, Jun
    Maekawa, Yuya
    Kanehashi, Shinji
    Shimomura, Takeshi
    POLYMERS, 2020, 12 (09)
  • [45] Direct sulfonation and photocrosslinking of unsaturated poly(styrene-b-butadiene-b-styrene) for proton exchange membrane of direct methanol fuel cell
    Kim, Seulgi
    Lee, Hyunjung
    Ahn, Dahee
    Park, Hae Woong
    Chang, Taihyun
    Lee, Wonmok
    JOURNAL OF MEMBRANE SCIENCE, 2013, 427 : 85 - 91
  • [46] Study of the Morphology and Rheological Behavior of Polymer-Modified Asphalt Blends Prepared with Poly(Styrene-b-Butadiene-b-Styrene) and Poly(Styrene-b[(Butadiene)1-x-(Ethylene-co-Butylene)x]-b-Styrene) of Star-Like Molecular Architecture
    Gonzalez Aguirre, Paola
    Medina Torres, Luis
    Fonteix, Christian
    Pla, Fernand
    Herrera Najera, Rafael
    POLYMER ENGINEERING AND SCIENCE, 2013, 53 (11): : 2454 - 2464
  • [47] STUDIES ON STRESS-RELAXATION OF STYRENE BUTADIENE RUBBER MICA COMPOSITES
    DEBNATH, S
    POLYMER TESTING, 1989, 8 (02) : 109 - 118
  • [48] Influences of Dicumyl Peroxide on Morphology and Mechanical Properties of Polypropylene/Poly(styrene-b-butadiene-b-styrene) Blends via Vane-Extruder
    Yang, Li
    Huang, Jintao
    Lu, Xiang
    Jia, Shikui
    Zhang, Haichen
    Jin, Gang
    Qu, Jinping
    JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (09)
  • [49] Electrostatic force microscopy measurements of CdSe-PS nanoparticles and CdSe-PS/poly(styrene-b-butadiene-b-styrene) nanocomposites
    Etxeberria, Haritz
    Tercjak, Agnieszka
    Mondragon, Iaki
    Eceiza, Arantxa
    Kortaberria, Galder
    COLLOID AND POLYMER SCIENCE, 2014, 292 (01) : 229 - 234
  • [50] Effect of compositon on the viscoelastic relaxation and phase morphology of linear styrene-butadiene-styrene triblock copolymers
    Du Miao
    Lu Yi
    Yu Qiuming
    Zheng Qiang
    ACTA POLYMERICA SINICA, 2008, (06) : 555 - 560
12345