ENTHALPY AND BOILING POINTS IN CAPILLARY COLUMN GAS-CHROMATOGRAPHY

被引：5
|
作者：
HANAI, T [1 ]
HATANO, H [1 ]
NIMURA, N [1 ]
KINOSHITA, T [1 ]
机构：
[1] KITASATO UNIV,SCH PHARMACEUT SCI,TOKYO 108,JAPAN
来源：
ANALYTICAL SCIENCES | 1993年 / 9卷 / 01期
关键词：
CAPILLARY COLUMN GAS CHROMATOGRAPHY; BOILING POINT PREDICTION; ENTHALPY; COMPUTATIONAL CHEMISTRY;
D O I：
10.2116/analsci.9.43
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The van der Waals volume and enthalpy of alkanes and alkylalcohols were calculated using the CAChe-MOPAC-BlogP program. These values were correlated with van der Waals volumes calculated by Bondi's method and enthalpies measured using a capillary column gas chromatograph. Further, the boiling points were analyzed by using their capacity ratios and physicochemical properties. The proposed boiling point of the alkanes and alkylalcohols are presented.
引用
收藏
页码：43 / 46
页数：4
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