EXCESS MOLAR VOLUMES OF N-PENTANOL + CUMENE, N-PENTANOL + 1,4-DIOXANE AND CUMENE + 1,4-DIOXANE AT DIFFERENT TEMPERATURES

被引：9

作者：

PEDROSA, GC ^{[1
]}

SALAS, JA ^{[1
]}

KATZ, M ^{[1
]}

机构：

[1] UNIV NACL TUCUMAN,FAC CIENCIAS EXACTAS & TECNOL,INST INGN QUIM,CATEDRA FISICOQUIM,RA-4000 TUCUMAN,ARGENTINA

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 1990年 / 21卷 / 04期

关键词：

4-dioxane cumene + 1; 4-dioxane Prigogine-Flory-Patterson theory; Excess molar volumes densities n-pentanol + cumene n-pentanol + 1;

D O I：

10.1080/00319109008028486

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molar excess volumes (VE) and partial molar excess volumes (VE) are reported for non-electrolyte binary mixtures of n-pentanol + cumene, n-pentanol + 1,4-dioxane and cumene + 1,4-dioxane at four temperatures and over the whole concentration range. In these systems, the n-pentanol is a highly polar molecule with association in its pure state, while the others two show little polarity without association in their pure states. The results of VEare discussed in terms of the interactions between components. The Prigogine-Flory-Patterson model of solution thermodynamics has been used to predict VE. This work shows the importance of the three contributions Δkint, AΔPand ΔVFto VE. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：207 / 216

页数：10

共 50 条

[31] SYSTEM WATER/1,4-DIOXANE
ROSSO, JC
CARBONNE.L
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1971, 272 (02): : 136 - &
[32] Hydrochlorothiazide-1,4-dioxane(1/1)
Johnston, A
Florence, AJ
Kennedy, AR
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2573 - O2575
[33] EXCESS VOLUMES AND EXCESS HEAT-CAPACITIES OF OXANE + CYCLOHEXANE AND 1,4-DIOXANE + CYCLOHEXANE
INGLESE, A
GROLIER, JPE
WILHELM, E
FLUID PHASE EQUILIBRIA, 1984, 15 (03) : 287 - 294
[34] HYDROQUINONE-1,4-DIOXANE (1/1)
BARNES, JC
PATON, JD
BLYTH, CS
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1183 - 1184
[35] Excess molar enthalpies of 1,3-dioxolane,or 1,4-dioxane with isomeric butanols
Gascón, I
Artigas, H
Martín, S
Cea, P
Lafuente, C
JOURNAL OF CHEMICAL THERMODYNAMICS, 2002, 34 (09): : 1351 - 1360
[36] Activation of cellulose by 1,4-dioxane for dissolution in N,N-dimethylacetamide
Raus, Vladimir
Sturcova, Adriana
Dybal, Jiri
Slouf, Miroslav
Vackova, Tatana
Salek, Petr
Kobera, Libor
Vlcek, Petr
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
[37] EXCESS GIBBS ENERGIES AND EXCESS VOLUMES OF THE MIXTURES ETHANOIC ACID + 1,4-DIOXANE AND OXOLANE
KALALI, HE
DEMIRIZ, AM
BUDDE, J
KOHLER, F
DALLOS, A
RATKOVICS, F
FLUID PHASE EQUILIBRIA, 1990, 54 : 111 - 120
[38] EXCESS MOLAR VOLUMES OF METHYLCYCLOHEXANE+BENZENE, +METHYLBENZENE, +1,4-DIOXANE, AND +TETRAHYDROFURAN AT 303.15K
JAIN, DVS
SINGLA, VK
SAINI, SB
SIDHU, RS
JOURNAL OF CHEMICAL THERMODYNAMICS, 1983, 15 (12): : 1105 - 1107
[39] THERMAL POLYMERIZATION OF N-TERT-BUTYLACRYLAMIDE IN 1,4-DIOXANE
ASIKOGLU, B
KILIC, S
BAYSAL, BM
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1985, 23 (04) : 1017 - 1029
[40] THERMODYNAMIC MIXING EFFECTS OF SYSTEMS WATER(1)-1,4-DIOXANE(2) AND METHANOL(1)-1,4-DIOXANE(2) - COMPARISON
KORTUM, G
VALENT, V
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1977, 81 (08): : 752 - 761

← 1 2 3 4 5 →