Beta-succinic acid, a crystal of extreme elastic anisotropy

被引:4
|
作者
Haussuhl, S
机构
[1] Universität Köln, Institut für Kristallographie, 50674 Köln
来源
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1995年 / 210卷 / 12期
关键词
Elasticity Thermoelasticity Thermal expansion Anisotropy; succinic acid;
D O I
10.1524/zkri.1995.210.12.903
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Single crystals of monoclinic beta-succinic acid, (CH2)(2)(COOH)(2) possess an extreme anisotropy of the longitudinal elastic stiffness. The maximum of 12.56 x 10(10) Nm(-2) is observed along the hydrogen-bonded infinite chains, the minimum of 0.99 x 10(10) Nm(-2) near a perpendicular direction within the cleavage plane (010). This anisotropy is the largest hitherto found in ionic or molecular crystals. The tensor of thermal expansion exhibits a considerable anisotropy, too, in accordance with the Grueneisen rule.
引用
收藏
页码:903 / 904
页数:2
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