EPOXIDATION OF ALKENES WITH O-2 CATALYZED BY EUCL3 UNDER AMBIENT CONDITIONS

被引：16
|
作者：
YAMANAKA, I
NAKAGAKI, K
AKIMOTO, T
OTSUKA, K
机构：
来源：
CHEMISTRY LETTERS | 1994年 / 09期
关键词：
D O I：
10.1246/cl.1994.1717
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
EuCl3 dissolved in a mixture of propanoic acid and 1,2-dichloroethane catalyzed the epoxidation of 1-hexene (81.4% selectivity, 5.34% yield for 1 h) with O-2 in the presence of Zn powder at 40 degrees C. The epoxidation was also catalyzed by LaCl3 (0.75% yield) and SmCl3 (0.57% yield), but CeCl3 (0.08% yield) was inactive. Epoxidations of styrene and cyclohexene were also promoted by the EuCl3-catalytic system.
引用
收藏
页码：1717 / 1720
页数：4
相关论文
共 50 条
  • [41] Simple and Rapid Synthesis of α-Fe2O3 Nanowires Under Ambient Conditions
    Nasibulin, Albert G.
    Rackauskas, Simas
    Jiang, Hua
    Tian, Ying
    Mudimela, Prasantha Reddy
    Shandakov, Sergey D.
    Nasibulina, Larisa. I.
    Sainio, Jani
    Kauppinen, Esko I.
    NANO RESEARCH, 2009, 2 (05) : 373 - 379
  • [42] Epoxidation of Alkenes with Molecular Oxygen as the Oxidant in the Presence of Nano-Al2O3
    Zhou, Xuan
    Wang, Qiong
    Xiong, Wenfang
    Wang, Lu
    Ye, Rongkai
    Xiang, Ge
    Qi, Chaorong
    Hu, Jianqiang
    SYNLETT, 2020, 31 (18) : 1789 - 1794
  • [43] PREDICTION OF THE O-2 CONDITIONS IN THE SELECTOR
    KRUIT, J
    BOLEY, F
    JACOBS, LJAM
    WOUDA, TWM
    WATER SCIENCE AND TECHNOLOGY, 1994, 29 (07) : 229 - 237
  • [44] Effective electric field: Quantifying the sensitivity of searches for new P, T-odd physics with EuCl3 •6H2O
    Sushkov, A. O.
    Sushkov, O. P.
    Yaresko, A.
    PHYSICAL REVIEW A, 2023, 107 (06)
  • [45] Dibromination of alkenes with LiBr and H2O2 under mild conditions
    Martins, Nayara Silva
    Alberto, Eduardo E.
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (01) : 161 - 167
  • [46] Efficient Epoxidation of Electron-Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ-PW10O38V2(μ-OH)2]3-
    Kamata, Keigo
    Sugahara, Kosei
    Yonehara, Kazuhiro
    Ishimoto, Ryo
    Mizuno, Noritaka
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (27) : 7549 - 7559
  • [47] Cobalt tetraarylporphyrin-catalysed epoxidation of alkenes by dioxygen and 2-methylpropanal under fluorous biphasic conditions
    Pozzi, G
    Montanari, F
    Quici, S
    CHEMICAL COMMUNICATIONS, 1997, (01) : 69 - 70
  • [48] High-Performance Electrohydrogenation of N2 to NH3 Catalyzed by Multishelled Hollow Cr2O3 Microspheres under Ambient Conditions
    Zhang, Ya
    Qiu, Weibin
    Ma, Yongjun
    Luo, Yonglan
    Tian, Ziqi
    Cui, Guanwei
    Xie, Fengyu
    Chen, Liang
    Li, Tingshuai
    Sun, Xuping
    ACS CATALYSIS, 2018, 8 (09): : 8540 - 8544
  • [49] EPOXIDATION OF CYCLOHEXENE CATALYZED BY COPPER(II) COMPLEXES UNDER MUKAIYAMAS CONDITIONS
    CORAIN, B
    TESSARI, A
    ZECCA, M
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (01) : L9 - L10
  • [50] Efficient Epoxidation of alkenes with aqueous hydrogen peroxide catalyzed by methyltrioxorhenium and 3-cyanopyridine
    Adolfsson, H
    Copéret, C
    Chiang, JP
    Yudin, AK
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (25): : 8651 - 8658
12345