ENTHALPIES OF SOLUTION AND INTERMOLECULAR FORCES - TERT-BUTYL HALIDES IN HYDROXYLIC SOLVENTS

被引：16
|
作者：
GONCALVES, RMC [1 ]
ALBUQUERQUE, LMPC [1 ]
MARTINS, FEL [1 ]
SIMOES, AMN [1 ]
RAMOS, JJM [1 ]
机构：
[1] Univ Tecn Lisboa, CTR QUIM FIS MOLEC, INST SUPER TECN, P-1096 LISBON, PORTUGAL
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1992年 / 5卷 / 02期
关键词：
D O I：
10.1002/poc.610050205
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The application of cavity theories of solution and linear solvation energy relationships to the interpretation of enthalpy of solution values of tert-butyl halides in hydroxylic media, measured at 25-degrees-C and infinite dilution, is deserted, in order to define the intermolecular forces acting between solutes and solvents. It is concluded that solvent dipolarity and solvent HBD acidity effects dominate the solution process. An empirical equation relating the enthalpies of solution with selected properties of both solvents and solutes is proposed. New experimental DELTA-H(s)infinity values for tert-butyl iodide in 13 alcohols are reported.
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收藏
页码：93 / 100
页数：8
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