ENTHALPIES OF SOLUTION AND INTERMOLECULAR FORCES - TERT-BUTYL HALIDES IN HYDROXYLIC SOLVENTS

被引：16

作者：

GONCALVES, RMC ^{[1
]}

ALBUQUERQUE, LMPC ^{[1
]}

MARTINS, FEL ^{[1
]}

SIMOES, AMN ^{[1
]}

RAMOS, JJM ^{[1
]}

机构：

[1] Univ Tecn Lisboa, CTR QUIM FIS MOLEC, INST SUPER TECN, P-1096 LISBON, PORTUGAL

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1992年 / 5卷 / 02期

关键词：

D O I：

10.1002/poc.610050205

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The application of cavity theories of solution and linear solvation energy relationships to the interpretation of enthalpy of solution values of tert-butyl halides in hydroxylic media, measured at 25-degrees-C and infinite dilution, is deserted, in order to define the intermolecular forces acting between solutes and solvents. It is concluded that solvent dipolarity and solvent HBD acidity effects dominate the solution process. An empirical equation relating the enthalpies of solution with selected properties of both solvents and solutes is proposed. New experimental DELTA-H(s)infinity values for tert-butyl iodide in 13 alcohols are reported.

引用

页码：93 / 100

页数：8

共 50 条

[1] THE REACTION OF ISOPRENE WITH TERT-BUTYL HYPOCHLORITE IN HYDROXYLIC SOLVENTS
OROSHNIK, W
MALLORY, RA
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (10) : 4608 - 4613
[2] QUANTITATIVE FORMULATION OF REACTIVITY IN TERMS OF SOLVENT AND SUBSTRATE PROPERTIES - SOLVOLYSIS OF TERT-BUTYL HALIDES IN HYDROXYLIC SOLVENTS
GONCALVES, RMC
SIMOES, AMN
ALBUQUERQUE, LMPC
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1991, (06): : 825 - 828
[3] LINEAR SOLVATION-ENERGY RELATIONSHIPS - SOLVOLYTIC REACTIONS OF TERT-BUTYL BROMIDE AND TERT-BUTYL IODIDE IN HYDROXYLIC SOLVENTS
GONCALVES, RMC
SIMOES, AMN
ALBUQUERQUE, LMPC
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (08): : 1379 - 1383
[4] THE EFFECT OF HYDROXYLIC SOLVENTS ON THE SOLVOLYSIS OF TERT-BUTYL CHLORIDE - CALCULATION OF THE CAVITY TERMS
ABRAHAM, MH
NASEHZADEH, A
MOURARAMOS, JJ
REISSE, J
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (06): : 854 - 859
[5] ENTHALPIES OF SOLUTION OF TERT-BUTYL CHLORIDE AND BROMIDE IN BUTANOLS AND PENTANOLS
GONCALVES, RMC
SIMOES, AMN
JOURNAL OF SOLUTION CHEMISTRY, 1990, 19 (03) : 315 - 320
[6] FEATURES OF THE HYDROLYSIS OF TERT-BUTYL HALIDES AND DIPHENYLMETHYL HALIDES IN PROTIC AND APROTIC-SOLVENTS
PONOMAREVA, EA
DVORKO, GF
KULIK, NI
EVTUSHENKO, NI
DOKLADY AKADEMII NAUK SSSR, 1983, 272 (02): : 373 - 376
[7] A criterion for the mechanism of the reaction between alkyl halides and hydroxylic solvents reactions of tert -butyl chloride
Bateman, LC
Hughes, DE
Ingold, CK
JOURNAL OF THE CHEMICAL SOCIETY, 1938, : 881 - 887
[8] TRANSFER ENTHALPIES OF TERT-BUTYL CHLORIDE IN SOME AQUO-ORGANIC SOLVENTS
DATTA, M
DAS, ML
DATTA, J
KUNDU, KK
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1993, 32 (06): : 472 - 477
[9] REACTIVITY OF DIMETHYLSULFOXIDE WITH TERT-BUTYL HALIDES
DOSSENA, A
MARCHELLI, R
CASNATI, G
CHIMICA & L INDUSTRIA, 1982, 64 (03): : 171 - 171
[10] KINETICS OF TERT-BUTYL ALCOHOL REACTION WITH TERT-BUTYL ALCOHOL WITH PHENYLISOCYANATE IN APROTON SOLVENTS
IVANOV, MG
KURYSHEVA, LM
DERGUNOV, YI
MULYANOV, PV
ZHURNAL OBSHCHEI KHIMII, 1990, 60 (07): : 1629 - 1632

← 1 2 3 4 5 →