A STABLE COMPOUND WITH A FORMAL TIN CARBON DOUBLE-BOND - THE BIS(2,4,6-TRIISOPROPYLPHENYL)(FLUORENYLIDENE)STANNENE

被引：53

作者：

ANSELME, G ^{[1
]}

RANAIVONJATOVO, H ^{[1
]}

ESCUDIE, J ^{[1
]}

COURET, C ^{[1
]}

SATGE, J ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,CHIM ORGANOMINERAUX LAB,URA 477,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 08期

关键词：

D O I：

10.1021/om00044a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(2,4,6-triisopropylphenyl)(fluorenylidene)stannene-diethyl ether (1a), a new stable compound with a formal tin-carbon double bond, has been synthesized by dehydrofluorination of the corresponding fluoro-stannane with tert-butyllithium; it has been characterized by NMR (delta(Sn-119) + 288 ppm, delta(C-13) + 133.85 ppm) and UV spectroscopy (lambda(max) 542 nm) and by electrophilic addition reactions to the tin-carbon unsaturation,

引用

页码：2748 / 2750

页数：3

共 50 条

[21] 1,5-Bis[2,6-bis(2,4,6-triisopropylphenyl)phenyl]-2,3,4,6,7-pentatellura-1,5-distannabicyclo[3.1.1]heptane
Saito, Masaichi
Hashimoto, Hizuru
Tajima, Tomoyuki
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M885 - U273
[22] 2,2-DIMESITYL-1-(2,4,6-TRI-TERT-BUTYLPHENYL)GERMAPHOSPHENE - THE 1ST STABLE COMPOUND WITH A GERMANIUM PHOSPHORUS DOUBLE-BOND
ESCUDIE, J
COURET, C
SATGE, J
ANDRIANARISON, M
ANDRIAMIZAKA, JD
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (11) : 3378 - 3379
[23] Correlations between microstructural characterization and thermal properties of well defined poly(ε-caprolactone) samples by ring opening polymerization with neutral and cationic bis(2,4,6-triisopropylphenyl)tin(IV) compounds
Gorrasi, Giuliana
Vertuccio, Luigi
Annunziata, Liana
Pellecchia, Claudio
Pappalardo, Daniela
REACTIVE & FUNCTIONAL POLYMERS, 2010, 70 (03): : 151 - 158
[24] Steric stabilisation of the P-P bond in a bulky tetraorganodiphosphine: synthesis, characterisation and X-ray structure determination of tetrakis(2,4,6-triisopropylphenyl)diphosphine
Brady, FJ
Cardin, CJ
Cardin, DJ
Wilcock, DJ
INORGANICA CHIMICA ACTA, 2000, 298 (01) : 1 - 8
[25] A donor-acceptor adduct: sterically encumbered terphenyl dichloro[2,6-bis(2,4,6-triisopropylphenyl)phenyl]dichloro(pyridine)gallium benzene hemisolvate
Twamley, B
Power, PP
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2001, 57 : m88 - M91
[26] REDUCTIVE COUPLING OF NITRILES VIA FORMAL [2 + 2] CYCLO-ADDITIONS TO THE TITANIUM CARBON DOUBLE-BOND
DOXSEE, KM
FARAHI, JB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) : 7239 - 7240
[27] PROPERTIES OF CHALCOGEN CHALCOGEN BONDS .13. REVERSIBLE DISMUTATION AND COORDINATION OF BIS(2,4,6-TRIISOPROPYLPHENYL) DISELENIDE WITH IODINE - A MODEL STUDY THAT RELATES TO IODINE INTERCALATION BETWEEN SELENIUM CHAINS
DUMONT, WW
MARTENS, A
POHL, S
SAAK, W
INORGANIC CHEMISTRY, 1990, 29 (24) : 4847 - 4848
[28] ELECTROOXIDATIVE FISSION OF CARBON-CARBON DOUBLE-BOND IN A K2OSO2(OH)(4)/HIO4 DOUBLE MEDIATORY SYSTEM
TANAKA, H
KIKUCHI, R
BABA, M
TORII, S
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (10) : 2989 - 2992
[29] 2+2 PHOTOCYCLOADDITION TO A CARBON NITROGEN DOUBLE-BOND .2. 2-PHENYL-2-OXAZOLIN-4-ONE
KOCH, TH
RODEHORS.RM
TETRAHEDRON LETTERS, 1972, (39) : 4039 - &
[30] A stable neutral silaaromatic compound, 2-{2,4,6-tris[bis(trimethylsilyl)methyl]phenyl}-2-silanaphthalene
Tokitoh, N
Wakita, K
Okazaki, R
Nagase, S
Schleyer, PV
Jiao, HJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (29) : 6951 - 6952

← 1 2 3 4 5 →