PREPARATION OF (C6F5)2SF+MF6-(M=AS,SB) AND CRYSTAL-STRUCTURE OF (C6F5)SF+SBF6-

被引：13
|
作者：
MINKWITZ, R
NOWICKI, G
PREUT, H
机构：
[1] Fachbereich Chemie Der Universität, Dortmund
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 611卷 / 05期
关键词：
(C6F5)2SF+SBF6-; PREPARATION; CRYSTAL STRUCTURE; SPECTROSCOPIC DATA;
D O I：
10.1002/zaac.19926110504
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
XeF+MF6- (M = As, Sb) reacts with (C6F5)2S in HF to form (C6F5)2SF+MF6-. The deeply violet sulfonium salts can be kept without decomposition up to 24 h at room temperature. The hexafluoroantimonate salt crystallizes in the monoclinic space group P2(1)/n with a = 1056.4(7) pm, b = 1446.3(10) pm, c = 1102.9(8) pm, beta = 91.29(6)-degrees und Z = 4. The SF-bond distance with 158.4(3) pm is of unusual length. Cations and anions are connected via interionic fluorine contacts to an infinite chain, in which cations and anions form to ABAB sequence along the chain.
引用
收藏
页码：23 / 27
页数：5
相关论文
共 50 条
  • [31] [(C6F5)2IF2][BF4], the first salt with the electrophilic cation [(C6F5)2IF2]+:: Synthesis, reactivity, and structure
    Frohn, Hermann-Josef
    Wenda, Andre
    Floerke, Ulrich
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (04): : 764 - 770
  • [32] Crystal structure of the strongly hydrogen bonded complex anion [(C6F5)3B(H3O2)B(C6F5)3]-
    Drewitt, MJ
    Niedermann, M
    Baird, MC
    INORGANICA CHIMICA ACTA, 2002, 340 : 207 - 210
  • [33] Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg•0.5C6F5 COOH and C6F5 COOAg
    Malkerova, I. P.
    Kayumova, D. B.
    Belova, E. V.
    Shmelev, M. A.
    Sidorov, A. A.
    Eremenko, I. L.
    Alikhanyan, A. S.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (02) : 84 - 88
  • [34] Synthesis and reactivity of [N(C6H4Br)3][B(C6F5)4]:: the X-ray crystal structure of [Fe(C5H5)2][B(C6F5)4]
    O'Connor, AR
    Nataro, C
    Golen, JA
    Rheingold, AL
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (14) : 2411 - 2414
  • [35] NOVEL ANIONIC ARYL COMPLEXES OF RH-III - [RH(C6F5)5]2- AND [RH(C6F5)4(CO)2]-
    GARCIA, MP
    ORO, LA
    LAHOZ, FJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (12): : 1700 - 1702
  • [36] Solution structures and exchange phenomena of the new alkene polymerization initiators (eta-C5Me5)TiMe(E)(mu-Me)B(C6F5)(3) (E=C6F5, OC6F5) and [(eta-C5Me5)Ti(OC6F5)(2)][BMe(C6F5)(3)]
    Tremblay, TL
    Ewart, SW
    Sarsfield, MJ
    Baird, MC
    CHEMICAL COMMUNICATIONS, 1997, (09) : 831 - 832
  • [37] REACTIVITY OF (NBU4)2[(C6F5)4PTTIPT(C6F5)4] - SYNTHESIS OF HETEROMETALLIC COMPOUNDS WITH PLATINUM
    FORNIES, J
    GARDE, R
    TOMAS, M
    USON, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 496 - INOR
  • [38] New weakly coordinating counter anions for high activity polymerisation catalysts:: [(C6F5)3B-CN-B(C6F5)3]- and [Ni{CNB(C6F5)3}4]2-
    Lancaster, SJ
    Walker, DA
    Thornton-Pett, M
    Bochmann, M
    CHEMICAL COMMUNICATIONS, 1999, (16) : 1533 - 1534
  • [39] The reactivity of perfluoroaryltellurium(IV) dihalides towards cyanide, crystal structures of (C6F5)3TeCl and C6F5TeTeC6F5
    Klapötke, TM
    Krumm, B
    Mayer, P
    Polborn, K
    Ruscitti, OP
    JOURNAL OF FLUORINE CHEMISTRY, 2001, 112 (02) : 207 - 212
  • [40] Reactivity of the bis(pentafluorophenyl)boranes ClB(C6F5)2 and [HB(C6F5)2]n towards late transition metal reagents
    Al-Fawaz, A
    Aldridge, S
    Coombs, DL
    Dickinson, AA
    Willock, DJ
    Ooi, LL
    Light, ME
    Coles, SJ
    Hursthouse, MB
    DALTON TRANSACTIONS, 2004, (23) : 4030 - 4037
12345