6-(4-Methylphenyl)-1,3,5-triazine-2,4-diamine-4-methylbenzoic acid (1/1)

被引:2
|
作者
Thanigaimani, Kaliyaperumal [1 ]
Arshad, Suhana [1 ]
Razak, Ibrahim Abdul [1 ]
Makeshvaran, Duraisamy [2 ]
Balasubramani, Kasthuri [2 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Usm 11800, Penang, Malaysia
[2] Govt Arts Coll Autonomous, Dept Chem, Karur 639005, Tamil Nadu, India
关键词
D O I
10.1107/S1600536813013895
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The 4-methylbenzoic acid molecule of the title adduct, C10H11N5 center dot C8H8O2, is approximately planar with a dihedral angle of 6.3 (2)degrees between the carboxylic acid group and the benzene ring. In the triazine molecule, the plane of the triazine ring makes a dihedral angle of 29.2 (2)degrees with that of the adjacent benzene ring. In the crystal, the acid and base molecules are linked via N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds with an R-2(2) (8) motif, and the acid-base pairs are further connected via N-H center dot center dot center dot N hydrogen bonds with R22 (8) motifs, forming a supramolecular ribbon along [101]. Between the tapes, a weak C-H center dot center dot center dot pi interaction is observed.
引用
收藏
页码:O970 / +
页数:9
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